ArticleChemical science2025
Intrinsically chiral thermoresponsive assemblies from achiral clusters: enhanced luminescence and optical activity through tailor-made chiral additives.
Article in Chemical science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Chiral metal clusters, due to their intriguing optical properties and unique resemblance in size to biomolecules, have attracted a lot of attention in recent times as potential candidates for application in bio-detection and therapy. While several strategies are reported for the synthesis of optically active clusters, a facile approach that enhances a multitude of properties has remained a challenge. Herein, we report a simple strategy wherein the use of a chiral cationic surfactant, during the synthesis of achiral clusters, leads to the fabrication of chiral assemblies possessing enhanced luminescence and optical activity. The structural resemblance of the capping ligand, mercaptoundecanoic acid (MUA) to the co-surfactant, (+/-)-
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