Evidence map›Paper›PMID 39715026›Full record

ArticleChemSusChem2025

Aprotic Electrolytes Beyond Organic Carbonates: Transport Properties of LiTFSI Solutions in S-Based Solvents.

Vanessa Piacentini, Cataldo Simari, Emanuela Mangiacapre, Adriano Pierini, Antonio Gentile, Stefano Marchionna, Isabella Nicotera, Sergio Brutti, Enrico Bodo

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in ChemSusChem, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Vanessa PiacentiniDepartment of Chemistry, Sapienza University of Rome, P.le Aldo Moro 5, 00185, Rome, Italy.ORCID https://orcid.org/0000-0001-9284-7601
Cataldo SimariDepartment of Chemistry, University of Calabria, 87036, Arcavacata di Rende (CS), Italy.ORCID https://orcid.org/0000-0002-6154-5456
Emanuela MangiacapreDepartment of Chemistry, Sapienza University of Rome, P.le Aldo Moro 5, 00185, Rome, Italy.ORCID https://orcid.org/0000-0002-6845-9059
Adriano PieriniDepartment of Chemistry, Sapienza University of Rome, P.le Aldo Moro 5, 00185, Rome, Italy.ORCID https://orcid.org/0000-0002-8863-503X
Antonio GentileRicerca sul Sistema Energetico - RSE S.p.A., Via R. Rubattino 54, 20134, Milano, Italy.ORCID https://orcid.org/0000-0001-8705-2863
Stefano MarchionnaRicerca sul Sistema Energetico - RSE S.p.A., Via R. Rubattino 54, 20134, Milano, Italy.ORCID https://orcid.org/0000-0002-9142-9384
Isabella NicoteraDepartment of Chemistry, University of Calabria, 87036, Arcavacata di Rende (CS), Italy.ORCID https://orcid.org/0000-0002-4411-0573
Sergio BruttiDepartment of Chemistry, Sapienza University of Rome, P.le Aldo Moro 5, 00185, Rome, Italy.ORCID https://orcid.org/0000-0001-8853-9710
Enrico BodoDepartment of Chemistry, Sapienza University of Rome, P.le Aldo Moro 5, 00185, Rome, Italy.ORCID https://orcid.org/0000-0001-8449-4711

Funding

Centro Nazionale per la Mobilità Sostenibile (MOST) CN4 Spoke 13 Batterie e Trazione Elettrica CN4621845C7D1585Research Fund for the Italian Electrical System DM MITE n. 337SUDELBAT CN4621845C7D1585
6 · The paper itself

Abstract

This work illustrates a physico-chemical study of the structural, dynamic, and transport properties of electrolytes made of LiTFSI solutions in sulphoxide and sulphone solvent mixtures. Experimental measurements, by Raman and NMR spectroscopies, as well as electrochemical impedance spectroscopy, reveal the formation of a variety of ionic aggregates depending on the solvent composition that significantly affect the ion mobility and conductivity of the electrolyte. Mixtures containing tetrahydrothiophene-1-oxide exhibit a larger ion mobility due to a rapid exchange mechanism between solvent molecules, whereas the use of tetramethylene sulphone favors the formation of ionic aggregates due to the strong dipolar interactions between solvent molecules.

Indexed as

aprotic electrolytes, Lithium batteriesLiTFSIsulphonessulphoxides

Identifiers

PMID39715026
PMCPMC12051247

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.