Evidence map›Paper›PMID 39700340›Full record

ArticleJournal of the American Chemical Society2025

Mixed Ionic and Electronic Conductivity in a Tetrathiafulvalene-Phosphonate Metal-Organic Framework.

Catarina Ribeiro, Bowen Tan, Flávio Figueira, Ricardo F Mendes, Joaquín Calbo, Gonçalo Valente, Paula Escamilla, Filipe A Almeida Paz, João Rocha, Mircea Dincă and 1 more

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Charge-Transfer Assembly of Electrically Conductive Metal-Organic Cages.Angewandte Chemie (International ed. in English) · 2026
    Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Catarina RibeiroDepartment of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-393 Aveiro, Portugal.
Bowen TanDepartment of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts02139, United States.ORCID 0000-0002-5166-1541
Flávio FigueiraDepartment of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-393 Aveiro, Portugal.ORCID 0000-0002-3685-9736
Ricardo F MendesDepartment of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-393 Aveiro, Portugal.ORCID 0000-0001-8242-324X
Joaquín CalboInstituto de Ciencia Molecular (ICMol), Universidad de Valencia, c/Catedrático José Beltrán, 2, 46980 Paterna, Spain.ORCID 0000-0003-4729-0757
Gonçalo ValenteDepartment of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-393 Aveiro, Portugal.
Paula EscamillaCIQUS, Centro Singular de Investigación en Química Bioloxica e Materiais Moleculares, Departamento de Química-Física, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain.ORCID 0000-0002-6419-8891
Filipe A Almeida PazDepartment of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-393 Aveiro, Portugal.ORCID 0000-0003-2051-5645
João RochaDepartment of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-393 Aveiro, Portugal.ORCID 0000-0002-0417-9402
Mircea DincăDepartment of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts02139, United States.ORCID 0000-0002-1262-1264
Manuel SoutoDepartment of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-393 Aveiro, Portugal.ORCID 0000-0003-3491-6984

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Mixed ionic-electronic conductors have great potential as materials for energy storage applications. However, despite their promising properties, only a handful of metal-organic frameworks (MOFs) provide efficient pathways for both ion and electron transport. This work reports a proton-electron dual-conductive MOF based on tetrathiafulvalene(TTF)-phosphonate linkers and lanthanum ions. The formation of regular, partially oxidized TTF stacks with short S···S interactions facilitates electron transport via a hopping mechanism, reporting a room-temperature conductivity of 7.2 × 10

Identifiers

PMID39700340
PMCPMC11800380

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.