ReviewHeliyon2024
Recent advances in heterogeneous porous Metal-Organic Framework catalysis for Suzuki-Miyaura cross-couplings.
Review in Heliyon, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
2 citing papers in PubMed.
- Mechanochemical optimization and scope of triple and multiple Sonogashira couplings of triethynylbenzene for conjugated porous polymer synthesis.Scientific reports · 2026Article
- Copper-Based Metal-Organic Frameworks for Sustainable Catalysis: Mechanistic Insights, Stability, and Emerging Research Directions.ACS omega · 2026Review
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Suzuki-Miyaura coupling (SMC), a crucial C-C cross-coupling reaction, is still associated with challenges such as high synthetic costs, intricate work-ups, and contamination with homogeneous metal catalysts. Research intensely focuses on strategies to convert homogeneous soluble metal catalysts into insoluble powder solids, promoting heterogeneous catalysis for easy recovery and reuse as well as for exploring greener reaction protocols. Metal-Organic Frameworks (MOFs), recognized for their high surface area, porosity, and presence of transition metals, are increasingly studied for developing heterogeneous SMC. The molecular fence effect, attributed to MOF surface functionalization, helps preventing catalyst deactivation by aggregation, migration, and leaching during catalysis. Recent reports demonstrate the enhanced catalytic activity, selectivity, stability, application scopes, and potential of MOFs in developing greener heterogeneous synthetic methodologies. This review focuses on the catalytic applications of MOFs in SMC reactions, emphasizing developments after 2016. It critically examines the synthesis and incorporation of active metal species into MOFs, focusing on morphology, crystallinity, and dimensionality for catalytic activity induction. MOF catalysts are categorized based on their metal nodes in subsections, with comprehensive discussion on Pd incorporation strategies, catalyst structures, optimal SMC conditions, and application scopes, concluding with insights into challenges and future research directions in this important emerging area of MOF applications.
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Registered trials
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