Evidence map›Paper›PMID 39684102›Full record

ArticlePolymers2024

Enhanced Green Strength in a Polycarbonate Polyol-Based Reactive Polyurethane Hot-Melt Adhesive.

Alejandra Moyano-Vallejo, María Pilar Carbonell-Blasco, Carlota Hernández-Fernández, Francisca Arán-Aís, María Dolores Romero-Sánchez, Elena Orgilés-Calpena

Abstract read
In one paragraph

Article in Polymers, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Alejandra Moyano-VallejoINESCOP Footwear Technology Centre, Alemania 102, 03600 Elda, Alicante, Spain.ORCID 0000-0003-4071-1248
María Pilar Carbonell-BlascoINESCOP Footwear Technology Centre, Alemania 102, 03600 Elda, Alicante, Spain.ORCID 0000-0001-7843-072X
Carlota Hernández-FernándezINESCOP Footwear Technology Centre, Alemania 102, 03600 Elda, Alicante, Spain.ORCID 0009-0009-2995-5074
Francisca Arán-AísINESCOP Footwear Technology Centre, Alemania 102, 03600 Elda, Alicante, Spain.ORCID 0000-0002-5689-3683
María Dolores Romero-SánchezINESCOP Footwear Technology Centre, Alemania 102, 03600 Elda, Alicante, Spain.ORCID 0000-0003-0165-7752
Elena Orgilés-CalpenaINESCOP Footwear Technology Centre, Alemania 102, 03600 Elda, Alicante, Spain.ORCID 0000-0002-1490-7514

Funding

Instituto Valenciano de Competitividad Empresarial IMDEEA/2024/43/CIRCADH II
6 · The paper itself

Abstract

This study aimed to enhance the initial adhesion performance of reactive polyurethane hot-melt adhesives by using a bio-based polycarbonate polyol instead of traditional polyester or polyether polyols and by incorporating thermoplastic polyurethane (TPU) in varied proportions. Adhesives synthesized from bio-based polycarbonate polyols and polypropylene glycol with MDI as the isocyanate were characterized chemically, thermally, and mechanically (FTIR, DSC, plate-plate rheology, DMA, and T-peel strength test). Adding 10-15 wt.% TPU significantly improved green strength and initial adhesion at room temperature and after accelerated cooling. The bio-based polycarbonate polyol promotes superior flexibility at low temperatures compared to fossil-derived alternatives, aligning with sustainability objectives. The results showed that 10 wt.% TPU maximized green strength without compromising flexibility, whereas 15 wt.% TPU, though enhancing adhesion, reduced flexibility due to increased crystallinity. T-peel tests on footwear materials indicated that all the adhesives exceeded the EN 15307:2015 requirements, with the highest peel strength achieved after curing. These findings highlight the benefit of bio-based polycarbonate polyols and TPUs in achieving strong, flexible, and eco-friendly adhesives suitable for demanding applications.

Indexed as

bio-based polycarbonate polyolgreen strengthreactive polyurethane hot-melt adhesivesustainable adhesivethermoplastic polyurethane

Identifiers

PMID39684102
PMCPMC11644545

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.