Evidence map›Paper›PMID 39679899›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2025

Constructing Quasi-Localized High-Concentration Solvation Structures to Stabilize Battery Interfaces in Nonflammable Phosphate-Based Electrolyte.

Chenyang Shi, Mengran Wang, Zari Tehrani, Bo Hong, Mengnan Wang, Rui Tan, Serena Margadonna, Yanqing Lai, Maria Magdalena Titirici

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. High-Conductivity Electrolytes Screened Using Fragment- and Composition-Aware Deep Learning.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026
    Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Chenyang ShiSchool of Metallurgy and Environment, Central South University, Changsha, Hunan, 410083, China.
Mengran WangSchool of Metallurgy and Environment, Central South University, Changsha, Hunan, 410083, China.
Zari TehraniDepartment of Chemical Engineering, Swansea University, Swansea, SA1 8EN, UK.
Bo HongSchool of Metallurgy and Environment, Central South University, Changsha, Hunan, 410083, China.
Mengnan WangDepartment of Chemical Engineering, Imperial College London, London, SW7 2AZ, UK.
Rui TanDepartment of Chemical Engineering, Swansea University, Swansea, SA1 8EN, UK.ORCID https://orcid.org/0009-0001-9278-7327
Serena MargadonnaDepartment of Chemical Engineering, Swansea University, Swansea, SA1 8EN, UK.
Yanqing LaiSchool of Metallurgy and Environment, Central South University, Changsha, Hunan, 410083, China.
Maria Magdalena TitiriciDepartment of Chemical Engineering, Imperial College London, London, SW7 2AZ, UK.

Funding

Central South University Research Programme of Advanced Interdisciplinary Studies 2023QYJC005Fundamental Research Funds for Central Universities of the Central South University 2022ZZTS0405National Natural Science Foundation of China 52034011National Natural Science Foundation of China 52101278Royce Industrial Collaboration Grant RICP-R4-100029RSC researcher collaboration grant C23-8220221815Science and Technology Innovation Program of Hunan Province 2023RC3054Young Elite Scientists Sponsorship Program by CAST 2023QNRC001
6 · The paper itself

Abstract

Flame-retardant phosphate-based electrolytes effectively enhance lithium-ion battery safety but suffer from poor compatibility with graphite anodes and high-voltage cathodes, hindering scalability. Fluorinated phosphates, though widely used, increase interfacial resistance at the anode, degrading performance. In this work, carbonate solvents with strong polarity are introduced to prevent tris(2,2,2-trifluoroethyl) phosphate (TFEP) from participating in the solvation structure of lithium ions. This strategy forms a quasi-localized high-concentration solvation structure, thereby restricting the reduction of TFEP and its impact on the graphite anode. The LiNi

Indexed as

battery safetyflame‐retardant electrolytesfluorinated phosphatesmolecular designsolvation shell tuning

Identifiers

PMID39679899
PMCPMC11809392

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.