ArticleNanophotonics (Berlin, Germany)2024
Resonance theory of vibrational polariton chemistry at the normal incidence.
Article in Nanophotonics (Berlin, Germany), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
11 citing papers in PubMed.
- A macroscopic condensation theory for vibrational strong coupling effects.Nature communications · 2026Article
- Validating free spectral range tracking as a robust method for mitigating artifacts in VSC kinetics.RSC advances · 2026Article
- Resonant Enhancement of Photolysis through Plasmon-Vibrational Coupling.Journal of the American Chemical Society · 2026Article
- Polaritonic Control of Blackbody Infrared Radiative Dissociation.The journal of physical chemistry letters · 2025Article
- Polariton mediated electron transfer under the collective molecule-cavity coupling regime.Chemical science · 2025Article
- Theoretical Insights into the Resonant Suppression Effect in Vibrational Polariton Chemistry.Journal of the American Chemical Society · 2025Article
- Molecular Polarizability under Vibrational Strong Coupling.Journal of chemical theory and computation · 2025Article
- Strong Coupling of Organic Molecules 2023 (SCOM23).Nanophotonics (Berlin, Germany) · 2024Article
- Unraveling a Cavity-Induced Molecular Polarization Mechanism from Collective Vibrational Strong Coupling.The journal of physical chemistry letters · 2024Article
- Consequences of Vibrational Strong Coupling on Supramolecular Polymerization of Porphyrins.Journal of the American Chemical Society · 2024Article
- Resonance Enhancement of Vibrational Polariton Chemistry Obtained from the Mixed Quantum-Classical Dynamics Simulations.The journal of physical chemistry letters · 2023Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We present a theory that explains the resonance effect of the vibrational strong coupling (VSC) modified reaction rate constant at the normal incidence of a Fabry-Pérot (FP) cavity. This analytic theory is based on a mechanistic hypothesis that cavity modes promote the transition from the ground state to the vibrational excited state of the reactant, which is the rate-limiting step of the reaction. This mechanism for a single molecule coupled to a single-mode cavity has been confirmed by numerically exact simulations in our recent work in [J. Chem. Phys. 159, 084104 (2023)]. Using Fermi's golden rule (FGR), we formulate this rate constant for many molecules coupled to many cavity modes inside a FP microcavity. The theory provides a possible explanation for the resonance condition of the observed VSC effect and a plausible explanation of why only at the normal incident angle there is the resonance effect, whereas, for an oblique incidence, there is no apparent VSC effect for the rate constant even though both cases generate Rabi splitting and forming polariton states. On the other hand, the current theory cannot explain the collective effect when a large number of molecules are collectively coupled to the cavity, and future work is required to build a complete microscopic theory to explain all observed phenomena in VSC.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.