Augmented machine learning for sewage quality assessment with limited data.

Physical, chemical, and biological processes within sewers significantly alter sewage composition during conveyance. This leads to the formation of sulfide and methane-compounds that contribute to sewer corrosion and greenhouse gas emissions. Reliable modeling of these compounds is essential for effective sewer management, but the development of machine learning (ML) models is hindered by differences in data accessibility and sampling frequencies of water quality variables. Here we present a mechanistically enhanced hybrid (ME-Hybrid) model that combines mechanistic modeling with data-driven approaches. This model harmonizes datasets with varying sampling frequencies and generates synthetic samples for ML training, thereby enhancing the monitoring of methane and sulfide in sewers. The optimal ME-Hybrid model integrates the backpropagation neural network with mechanistic frequency harmonization. We demonstrate that the ME-Hybrid model outperforms pure ML and linear interpolation in capturing fluctuating trends and extremes of sulfide concentrations, achieving a coefficient of determination (R