Evidence map›Paper›PMID 39648203›Full record

ArticleLight, science & applications2024

Unlocking high-performance near-infrared photodetection: polaron-assisted organic integer charge transfer hybrids.

Muhammad Ahsan Iqbal, Xueqian Fang, Yasir Abbas, Xiaoliang Weng, Tingchao He, Yu-Jia Zeng

Abstract read
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Article in Light, science & applications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed
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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

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Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

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0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

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PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Muhammad Ahsan IqbalSchool of Environment and Civil Engineering, Dongguan University of Technology, Dongguan, 523808, China.ORCID http://orcid.org/0000-0002-5705-9316
Xueqian FangSchool of Environment and Civil Engineering, Dongguan University of Technology, Dongguan, 523808, China. studxfang@yeah.net.
Yasir AbbasSchool of Mechanical Engineering, Dongguan University of Technology, Dongguan, 523808, China.
Xiaoliang WengShenzhen Key Laboratory of Laser Engineering, Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen, 518060, China.
Tingchao HeShenzhen Key Laboratory of Laser Engineering, Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen, 518060, China.ORCID http://orcid.org/0000-0003-1040-0596
Yu-Jia ZengShenzhen Key Laboratory of Laser Engineering, Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen, 518060, China. yjzeng@szu.edu.cn.ORCID http://orcid.org/0000-0001-5673-3447

Funding

National Natural Science Foundation of China (National Science Foundation of China) 12172236National Natural Science Foundation of China (National Science Foundation of China) 52273298National Natural Science Foundation of China (National Science Foundation of China) 62250410366Shenzhen Science and Technology Innovation Commission JCYJ20210324095611032, JCYJ20220818100008016
6 · The paper itself

Abstract

Room temperature femtowatt sensitivity remains a sought-after attribute, even among commercial inorganic infrared (IR) photodetectors (PDs). While organic IR PDs are poised to emerge as a pivotal sensor technology in the forthcoming Fourth-Generation Industrial Era, their performance lags behind that of their inorganic counterparts. This discrepancy primarily stems from poor external quantum efficiencies (EQE), driven by inadequate exciton dissociation (high exciton binding energy) within organic IR materials, exacerbated by pronounced non-radiative recombination at narrow bandgaps. Here, we unveil a high-performance organic Near-IR (NIR) PD via integer charge transfer between Poly[2,5-bis(3-tetradecylthiophen-2-yl)thieno[3,2-b]thiophene] (C-14PBTTT) donor (D) and Tetrafluorotetracyanoquinodimethane (TCNQF4) acceptor (A) molecules, showcasing strong low-energy subgap absorptions up to 2.5 µm. We observe that specifically, polaron excitation in these radical and neutral D-A blended molecules enables bound charges to exceed the Coulombic attraction to their counterions, leading to an elevated EQE (polaron absorption region) compared to Frenkel excitons. As a result, our devices achieve a high EQE of ∼10

Identifiers

PMID39648203
PMCPMC11625827

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.