Evidence map›Paper›PMID 39639009›Full record

ArticleNature communications2024

Nondestructive halide exchange via S

Kai Zhang, Yang Shen, Long-Xue Cao, Zhen-Huang Su, Xin-Mei Hu, Shi-Chi Feng, Bing-Feng Wang, Feng-Ming Xie, Hao-Ze Li, Xingyu Gao and 2 more

Abstract read
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Article
  6. Article
  7. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Kai Zhang *Macao Institute of Materials Science and Engineering (MIMSE), Faculty of Innovation Engineering, Macau University of Science and Technology, Taipa, Macao, China.
Yang Shen *Macao Institute of Materials Science and Engineering (MIMSE), Faculty of Innovation Engineering, Macau University of Science and Technology, Taipa, Macao, China. yangshen@suda.edu.cn.ORCID http://orcid.org/0009-0004-1764-0570
Long-Xue Cao *Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou, China.
Zhen-Huang SuShanghai Synchrotron Radiation Facility, Zhangjiang Laboratory, Chinese Academy of Sciences, Shanghai, China.ORCID http://orcid.org/0000-0003-0026-2601
Xin-Mei HuInstitute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou, China.
Shi-Chi FengInstitute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou, China.
Bing-Feng WangSchool of Physics and Electronic Science, East China Normal University, Shanghai, China.
Feng-Ming XieInstitute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou, China.
Hao-Ze LiSchool of Physics and Electronic Science, East China Normal University, Shanghai, China.
Xingyu GaoShanghai Synchrotron Radiation Facility, Zhangjiang Laboratory, Chinese Academy of Sciences, Shanghai, China.
Yan-Qing LiSchool of Physics and Electronic Science, East China Normal University, Shanghai, China. yqli@phy.ecnu.edu.cn.ORCID http://orcid.org/0009-0001-1978-0516
Jian-Xin TangMacao Institute of Materials Science and Engineering (MIMSE), Faculty of Innovation Engineering, Macau University of Science and Technology, Taipa, Macao, China. jxtang@must.edu.mo.ORCID http://orcid.org/0000-0002-6813-0448

Funding

National Natural Science Foundation of China (National Science Foundation of China) 12075303National Natural Science Foundation of China (National Science Foundation of China) 62075061National Natural Science Foundation of China (National Science Foundation of China) 62320106004
6 · The paper itself

Abstract

Blue perovskite light-emitting diodes (PeLEDs) still remain poorly developed due to the big challenge of achieving high-quality mixed-halide perovskites with wide optical bandgaps. Halide exchange is an effective scheme to tune the emission color of PeLEDs, while making perovskites susceptible to high defect density due to solvent erosion. Herein, we propose a versatile strategy for nondestructive in-situ halide exchange to obtain high-quality blue perovskites with low trap density and tunable bandgaps through long alkyl chain chloride incorporated chloroform post-treatment. In comparison with conventional halide exchange method, the ionic exchange mechanism of the present strategy is similar to a bimolecular nucleophilic substitution process, which simultaneously modulates perovskite bandgaps and inhibits new halogen vacancy generation. Consequently, efficient PeLEDs across blue spectral regions are obtained, exhibiting external quantum efficiencies of 23.6% (sky-blue emission at 488 nm), 20.9% (pure-blue emission at 478 nm), and 15.0% (deep-blue emission at 468 nm), respectively.

Identifiers

PMID39639009
PMCPMC11621679

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.