Evidence map›Paper›PMID 39632863›Full record

ArticleNature communications2024

19.5% Inverted organic photovoltaic with record long-lifetime via multifunctional interface engineering featuring radical scavenger.

Jiaming Huang, Jiehao Fu, Bo Yuan, Hao Xia, Tianxiang Chen, Yongwen Lang, Heng Liu, Zhiwei Ren, Qiong Liang, Kuan Liu and 9 more

Abstract read
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

19 authors.

Jiaming Huang *Department of Electrical and Electronic Engineering, The Hong Kong Polytechnic University, Hong Kong, China.
Jiehao Fu *Department of Electrical and Electronic Engineering, The Hong Kong Polytechnic University, Hong Kong, China.
Bo Yuan *Department of Chemistry, City University of Hong Kong, Hong Kong, China.
Hao XiaDepartment of Electrical and Electronic Engineering, The Hong Kong Polytechnic University, Hong Kong, China.
Tianxiang ChenDepartment of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Kong, China.ORCID http://orcid.org/0000-0002-1578-0957
Yongwen LangDepartment of Electrical and Electronic Engineering, The Hong Kong Polytechnic University, Hong Kong, China.
Heng LiuDepartment of Physics, The Chinese University of Hong Kong, Hong Kong, China.
Zhiwei RenDepartment of Electrical and Electronic Engineering, The Hong Kong Polytechnic University, Hong Kong, China.ORCID http://orcid.org/0000-0001-9674-0588
Qiong LiangDepartment of Electrical and Electronic Engineering, The Hong Kong Polytechnic University, Hong Kong, China.
Kuan LiuDepartment of Electrical and Electronic Engineering, The Hong Kong Polytechnic University, Hong Kong, China.ORCID http://orcid.org/0000-0002-4874-141X
Zhiqiang GuanDepartment of Chemistry, City University of Hong Kong, Hong Kong, China.
Guangruixing ZouDepartment of Materials Science and Engineering; Center of Super-Diamond and Advance Films (COSDAF); School of Energy and Environment, City University of Hong Kong, Hong Kong, China.
Hrisheekesh Thachoth ChandranDepartment of Electrical and Electronic Engineering, The Hong Kong Polytechnic University, Hong Kong, China.
Tsz Woon Benedict LoDepartment of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Kong, China.ORCID http://orcid.org/0000-0002-4853-0196
Xinhui LuDepartment of Physics, The Chinese University of Hong Kong, Hong Kong, China.ORCID http://orcid.org/0000-0002-1908-3294
Chun-Sing LeeDepartment of Chemistry, City University of Hong Kong, Hong Kong, China.ORCID http://orcid.org/0000-0001-6557-453X
Hin-Lap YipDepartment of Materials Science and Engineering; Center of Super-Diamond and Advance Films (COSDAF); School of Energy and Environment, City University of Hong Kong, Hong Kong, China.ORCID http://orcid.org/0000-0002-5750-9751
Yung-Kang PengDepartment of Chemistry, City University of Hong Kong, Hong Kong, China.ORCID http://orcid.org/0000-0001-9590-6902
Gang LiDepartment of Electrical and Electronic Engineering, The Hong Kong Polytechnic University, Hong Kong, China. gang.w.li@polyu.edu.hk.ORCID http://orcid.org/0000-0001-8399-7771

Funding

Research Grants Council, University Grants Committee (RGC, UGC) 15221320Research Grants Council, University Grants Committee (RGC, UGC) C5037-18G
6 · The paper itself

Abstract

Advances in improving the operational lifetime of highly efficient organic photovoltaic (OPV) and understanding photo-degradation mechanisms in molecular level are currently limited, especially on the promising inverted OPV, posing critical challenges to commercialization. Here, we demonstrate a radical scavenger (3-(3,5-Di-tert-butyl-4-hydroxyphenyl)propionic acid) capped ZnO (BHT@ZnO) nanoparticles as the electron transport layer providing effective surface oxygen vacancy passivation and reactive radical capture capability. Encouragingly, this BHT@ZnO-based empowered device achieves a record inverted OPV efficiency of 19.47% (Certificated efficiency: 18.97%). The devices demonstrate light soaking-free behavior, long-term stability under ISOS-D-1 (94.2% PCE retention after 8904 h in ambient) and ISOS-L-1 testing protocol (81.5% PCE retention after 7724 h in MPP). More importantly, we elucidate detailed degradation mechanism in OPV involving selectively catalytic degradation of donor and acceptor by superoxide and hydroxyl radicals, respectively, as well as the degradation pathway of polymer donor upon radiation exposure. Performance enhancement and mechanism comprehension provide strong support for the development of OPV technology.

Identifiers

PMID39632863
PMCPMC11618627

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.