ArticleScientific reports2024
Anti-polyelectrolyte effect of zwitterions containing (meth)acrylic waterborne polymer chains as tool for colloidal stabilization and polymer reinforcement.
Article in Scientific reports, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
0 citing papers in PubMed.
No citing paper in PubMed yet.
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The anti-polyelectrolyte effect, a characteristic unique to polymer chains containing zwitterions, was investigated for its impact on colloidal stabilization during emulsion polymerization and on the resulting polymer characteristics. The zwitterionic monomer (ZM) 3-[(3-Acrylamidopropyl)dimethylammonio]propane-1-sulfonate (A3361) was selected for the synthesis of 30 wt% emulsifier-free methyl methacrylate/n-butyl acrylate (MMA/n-BA) polymer latex. Three pH conditions were examined: neutral, where the zwitterionic chains are in a collapsed state, and acidic and basic, where these chains adopt an extended conformation, leading to the anti-polyelectrolyte effect. The study of the anti-polyelectrolyte phenomenon on colloidal stability was challenging due to the increased ionic strength in the dispersions. Nevertheless, films cast from the acidic latex demonstrated enhanced mechanical properties, water resistance, and humidity barrier compared to films produced at neutral pH. This improvement is attributed to the anti-polyelectrolyte phenomenon, where the extended polymer chains rich in zwitterions offer enhanced ionic complexation, resulting in a denser and thicker ionic complexed network within the MMA/n-BA matrix. Under basic pH conditions, these improvements were modest, indicating that the anti-polyelectrolyte mechanism is influenced by pH. Furthermore, the high incorporation of A3361 facilitated, for the first time, the synthesis of 50% solids content emulsifier-free latexes, highlighting practical importance of this technology.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.