ArticleChemistry (Weinheim an der Bergstrasse, Germany)2025
Synthesis of Bis(diimino)palladium Nanosheets as Highly Active Electrocatalysts for Hydrogen Evolution.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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4 citing papers in PubMed.
- Lateral Size Governs Hydrogen Evolution Reaction Mechanisms and Kinetics of Ultrathin Pd Nanosheets in Acidic and Alkaline Electrolytes.The journal of physical chemistry. C, Nanomaterials and interfaces · 2026Article
- Highly Selective and Irreversible Anion-Exchange in Two-Dimensional Bis(terpyridine)metal(II) Polymer Thin Films.ACS applied materials & interfaces · 2026Article
- Rationally Engineered Heterometallic Metalladithiolene Coordination Nanosheets with Defined Atomic Arrangements.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Synthesis of Bis(diimino)palladium Nanosheets as Highly Active Electrocatalysts for Hydrogen Evolution.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
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Abstract
Development of efficient electrocatalysts for hydrogen evolution reactions (HERs) is necessary to achieve environmentally friendly and sustainable hydrogen production. To reduce cost and to circumvent the scarcity of platinum, the most efficient catalyst for HER, it is essential to develop catalysts using ubiquitous base metals or minimal amounts of precious metals. Bis(diimino)metal (MDI) coordination nanosheets are potential HER catalysts because their electric conductivities, two-dimensionality, and porous structures provide large surface areas and efficient mass and electron transfer. In addition, with sparse metal arrangements in their chemical structures, nanosheets can reduce the amount of metal needed. We synthesized bis(diimino)palladium coordination nanosheets (PdDI) as a coordination polymer composed of bis(diimino)palladium, with semiconducting characteristics, using gas-liquid interfacial synthesis and electrochemical oxidation. These electrochemically synthesized PdDIs exhibit remarkable catalytic performance with overpotential reaching 10 mA cm
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