ArticleBiomacromolecules2024
Borax Cross-Linked Acrylamide-Grafted Starch Self-Healing Hydrogels.
Article in Biomacromolecules, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Synthesis and Characterization of Biobased Superabsorbent Hydrogels: Cross-Linked Sodium Alginate‑ACS omega · 2026Article
- Natural Polymer-Based Mechanically Strong Hydrogel with Fast Self-Healing for Heavy Metal Ions Removal and Supercapacitor Applications.Polymers · 2026Article
- Hydrogels for Climate Change Mitigation: Applications in Water Harvesting, Passive Cooling, and Environmental Solutions.Gels (Basel, Switzerland) · 2025Review
- Removal of Textile Dye Mixture by FePolymers · 2025Article
- Stimuli-Responsive Starch-Based Biopolymer Coatings for Smart and Sustainable Fertilizers.Gels (Basel, Switzerland) · 2025Review
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The biocompatibility and renewability of starch-based hydrogels have made them popular for applications across various sectors. Their tendency to incur damage after repeated use limits their effectiveness in practical applications. Improving the mechanical properties and self-healing of hydrogels simultaneously remains a challenge. This study introduces a new self-healing hydrogel, synthesized by grafting acrylamide onto starch using ceric ammonium nitrate (CAN) as an initiator, followed by borax cross-linking. We systematically examined how the starch-to-monomer ratio, borax concentration, and CAN concentration impact the grafting reactions and overall performance of the hydrogels. The addition of borax significantly reinforced the strength of the hydrogel; the maximum storage modulus increased by 1.8 times. Thanks to dynamic borate ester and hydrogen bonding, the hydrogel demonstrated remarkable recovery properties and responsiveness to temperature. We expect that the present research could broaden the application of starch-based hydrogels in agriculture, sensors, and wastewater treatment.
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