Evidence map›Paper›PMID 39580478›Full record

ArticleNature communications2024

Alkali cation-π interactions in aqueous systems, modulating supramolecular stereoisomerism of nanoscopic metal-organic capsules.

Paul Wix, Swetanshu Tandon, Sebastien Vaesen, Kadri Karimu, Jennifer S Mathieson, Kane Esien, Solveig Felton, Graeme W Watson, Wolfgang Schmitt

Abstract read
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Building molecular CJournal of molecular modeling · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Paul WixSchool of Chemistry & SFI AMBER Research Centre, Trinity College Dublin, The University of Dublin, College Green, Dublin, D02 PN40, Ireland.
Swetanshu TandonSchool of Chemistry & SFI AMBER Research Centre, Trinity College Dublin, The University of Dublin, College Green, Dublin, D02 PN40, Ireland.ORCID http://orcid.org/0000-0002-0626-0626
Sebastien VaesenSchool of Chemistry & SFI AMBER Research Centre, Trinity College Dublin, The University of Dublin, College Green, Dublin, D02 PN40, Ireland.ORCID http://orcid.org/0000-0002-0823-9564
Kadri KarimuSchool of Chemistry & SFI AMBER Research Centre, Trinity College Dublin, The University of Dublin, College Green, Dublin, D02 PN40, Ireland.
Jennifer S MathiesonSchool of Chemistry, University of Glasgow, Joseph Black Building, University Ave, Glasgow, G12 8QQ, UK.
Kane EsienCentre for Quantum Materials and Technologies, School of Mathematics and Physics, Queen's University Belfast, BT7 1NN, Belfast, UK.
Solveig FeltonCentre for Quantum Materials and Technologies, School of Mathematics and Physics, Queen's University Belfast, BT7 1NN, Belfast, UK.ORCID http://orcid.org/0000-0002-4552-2123
Graeme W WatsonSchool of Chemistry & SFI AMBER Research Centre, Trinity College Dublin, The University of Dublin, College Green, Dublin, D02 PN40, Ireland.ORCID http://orcid.org/0000-0001-6732-9474
Wolfgang SchmittSchool of Chemistry & SFI AMBER Research Centre, Trinity College Dublin, The University of Dublin, College Green, Dublin, D02 PN40, Ireland. schmittw@tcd.ie.ORCID http://orcid.org/0000-0002-0058-9404

Funding

EC | EU Framework Programme for Research and Innovation H2020 | H2020 Priority Excellent Science | H2020 European Research Council (H2020 Excellent Science - European Research Council) ERC SUPRAMOL CoG 2014-647719Irish Research Council for Science, Engineering and Technology (IRCSET) GOIPG/2015/2713Irish Research Council for Science, Engineering and Technology (IRCSET) GOIPG/2015/2952Science Foundation Ireland (SFI) 13/IA/1896; 12/RC/2278_P2; 12/RC/2275_P2
6 · The paper itself

Abstract

Contrary to common chemical intuition, cation-π interactions can persist in polar, aqueous reaction solutions, rather than in dry non-coordinative solvent systems. This account highlights how alkali ion-π interactions impart distinctive structure-influencing supramolecular forces that can be exploited in the preparation of nanoscopic metal-organic capsules. The incorporation of alkali ions from polar solutions into molecular pockets promotes the assembly of otherwise inaccessible capsular entities whose structures are distinctive to those of common polyoxovanadate clusters in which {V=O} moieties usually point radially to the outside, shielding the molecular entities. The applied concept is exemplified by homologous {V

Identifiers

PMID39580478
PMCPMC11585540

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.