ArticleChemical science2025
Structural constraint at a P-P bond: phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism.
Article in Chemical science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- A molecular model for the Ge(100) buckled dimer.Nature chemistry · 2026Article
- Bis(pyridino-Inorganic chemistry · 2026Article
- Photochemical activation of pincer-ligated phosphoranides: mechanistic insight for reduction of aryl halides.Chemical science · 2026Article
- A focus on phosphinophosphination of apolar bonds by a structurally constrained P-P bonded system.Chemical science · 2025Article
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Structurally constraining p-block elements has become a powerful strategy for bond activation chemistry with main group compounds. Traditionally, this approach focuses on mononuclear centers, yet applying structural constraints to systems with element-element bonds remains underexplored. In this study, we introduce a cation featuring a structural constraint-elongated P-P bond that spontaneously adds to unactivated alkynes, alkenes, aldehydes, and ketones. Despite its positive charge, the surprisingly apolar P-P
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