ArticleChemical science2024
Noncentrosymmetric tellurite halides created by a depolymerization strategy: toward strong SHG intensity and wide bandgap.
Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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3 citing papers in PubMed.
- Breaking Inversion Symmetry via Vanadium Coordination Engineering in Bismuth Vanadium Selenites.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Recent progress in iodate based nonlinear optical crystals.Chemical science · 2026Review
- Halogen-ion-driven polymorphs for high-performance nonlinear optical crystalline materials.Chemical science · 2026Article
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Authors and funding
5 authors.
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Abstract
The design and synthesis of nonlinear optical (NLO) materials with a strong second harmonic generation (SHG) effect and wide band gap is a long-standing challenge because of their inverse relationship, especially for metal tellurites. We found that a lower degree of polymerization of tellurite groups corresponds to a higher proportion of non-centrosymmetric (NCS) structures formed. Based on Pauling's rule #4, introduction of cations (Al
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