ArticleJournal of the American Chemical Society2024
Functionalized Graphene via a One-Pot Reaction Enabling Exact Pore Sizes, Modifiable Pore Functionalization, and Precision Doping.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Lithium Ion-Conducting Triazacoronene-Based Neutral 2D Covalent Organic Framework as a Solid-State Electrolyte.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Recent advances in porous graphitic frameworks: a critical mini-review.RSC advances · 2025Review
- Covalent Organic Frameworks with 2‑Fold Functional Pores Produced from a Monofunctional Monomer as Predicted by Computational Methods.ACS polymers Au · 2025Article
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Authors and funding
10 authors.
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Abstract
Functionalizing graphene with exact pore size, specific functional groups, and precision doping poses many significant challenges. Current methods lack precision and produce random pore sizes, sites of attachment, and amounts of dopant, leading to compromised structural integrity and affecting graphene's applications. In this work, we report a strategy for the synthesis of functionalized graphitic materials with modifiable nanometer-sized pores via a Pictet-Spengler polymerization reaction. This one-pot, four-step synthesis uses concepts based on covalent organic frameworks (COFs) synthesis to produce crystalline two-dimensional materials that were confirmed by PXRD, TEM measurements, and DFT studies. These new materials are structurally analogous to doped graphene and graphene oxide (GO) but, unlike GO, maintain their semiconductive properties when fully functionalized.
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Registered trials
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