ArticleNature chemistry2025
Isolation and characterization of a triplet nitrene.
Article in Nature chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
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- Enhanced Resolution in EPR Spectroscopy Using para-Hydrogen Matrices.Angewandte Chemie (International ed. in English) · 2026Article
- An isolable germa-isonitrile featuring a terminal nitrogen-germanium triple bond.Nature chemistry · 2026Article
- Optically addressable molecular spin qubits.MRS bulletin · 2026Review
- Synthesis and Reactivity of a Mono-Coordinated Triplet Bismuthinidene.Angewandte Chemie (International ed. in English) · 2025Article
- Strain-Release Driven Arsenium Ion Bond Insertion.Angewandte Chemie (International ed. in English) · 2025Article
- Isolation and Characterization of an Organobismuth Dihydride.Journal of the American Chemical Society · 2025Article
- Isolation of kinetically-stabilised diarylchalcogenide radical cations.Communications chemistry · 2025Article
- Impact of Bulky Substituents on the Singlet Arylnitrene Ring Enlargement.The Journal of organic chemistry · 2025Article
- Reactivity of Pnictaalumenes Towards 1,3-Dipole Molecules.Angewandte Chemie (International ed. in English) · 2025Article
- Historical and Recent Developments in the Chemistry of Cyanate Congeners.Inorganic chemistry · 2025Review
- Article
- Transient Triplet Metallopnictinidenes M-Pn (M = PdJournal of the American Chemical Society · 2025Article
- Copper and Silver Trispyrazolylborate-Phosphinoazide Complexes: Synthesis, Characterization, and Nitrene Generation.Inorganic chemistry · 2025Article
- Direct Determination of a Giant Zero-Field Splitting of 5422 cmJournal of the American Chemical Society · 2025Article
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Authors and funding
6 authors.
Funding
Abstract
Nitrene radical compounds are short-lived intermediates in a variety of nitrogen-involved transformations. They feature either a singlet or a triplet ground state, depending on the electronic properties of the substituents. Triplet nitrenes are highly reactive and their isolation in the condensed phase under ambient conditions is challenging. Here we report the synthesis and isolation of a triplet arylnitrene supported by a bulky hydrindacene ligand. The arylnitrene is fully characterized by various spectroscopic and structural techniques including electron paramagnetic resonance spectroscopy and single-crystal X-ray diffraction. Its high stability is largely attributed to the steric hindrance and effective electron delocalization provided by the supporting ligand. Electron paramagnetic resonance spectroscopy in conjunction with highly correlated wavefunction-based ab initio calculations provides support for a triplet ground state nitrene with axial zero-field splitting D = 0.92 cm
Identifiers
39562811What OpenQuestion holds
Registered trials
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