ArticleAngewandte Chemie (International ed. in English)2025
Iodide Anion Enables a Reductive Cross-Electrophile Coupling for Preparing Tertiary Amines.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Eschenmoser's salts: from design to applications in organic synthesis.Organic chemistry frontiers : an international journal of organic chemistry · 2026Review
- A Precise Synthetic Toolbox: H-Bond-Assisted Quadruple Reactivity ofThe Journal of organic chemistry · 2025Article
- Iodide Anion Enables a Reductive Cross-Electrophile Coupling for Preparing Tertiary Amines.Angewandte Chemie (International ed. in English) · 2025Article
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Authors and funding
9 authors.
Funding
Abstract
The reducing power of iodide anion is an underexplored property that can be used for the cross-electrophile coupling of organic molecules. Herein we harness this trait for the preparation of tertiary amines through the combination of two simple reagents: an electrophilic-carbon precursor and an iminium iodide in a dual role - both as nitrogen-containing building block and as reducing agent. The underlying mechanism of this new C-C bond-formation paradigm is explored through a combination of experiment and quantum chemical calculations.
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Registered trials
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