ArticleChemistry (Weinheim an der Bergstrasse, Germany)2025
Metal Pyrazolyl-Diphosphonate Pillared Materials as Heterogeneous Catalysts in the Mukaiyama-Type Aerobic Olefin Epoxidation.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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2 citing papers in PubMed.
- Bispidine-Based Copper(II) Coordination Polymers with Remarkable Dynamic Properties, Selective Volatile Organic Compounds Adsorption, and Exchange Capabilities.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Metal Pyrazolyl-Diphosphonate Pillared Materials as Heterogeneous Catalysts in the Mukaiyama-Type Aerobic Olefin Epoxidation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
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4 authors.
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Abstract
The structural variability and chemical stability of metal phosphonates under harsh conditions are attractive attributes that have drawn considerable attention in recent years. As the need for more sustainable solutions rises, the demand for novel and tolerant materials also increases. Thus, herein we report, for the first time, the synthesis of a novel diphosphonic organic linker named pyrazole diphenyl phosphonate (PZDP), envisioning the fabrication of durable metal phosphonates. In view of this, a series of M-PZDP materials (M=Ca, Sr, Ba, Zn and Co) were synthesized employing either solvothermal or hydrothermal methods. The crystal structures of the Ca, Sr, Zn, and Co derivatives were determined revealing a 2D-pillared architecture. Zn-PZDP is an anionic framework with dimethylammonium cations. The Co-PZDP compound was tested as a heterogeneous catalyst in olefin epoxidation employing molecular oxygen.
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