Structure and thermal stability of phosphorus-iodonium ylids.

Andrew Greener, Stephen P Argent, Coby J Clarke, Miriam L O'Duill

Abstract read

In one paragraph

Article in Beilstein journal of organic chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it

0cells of the map it votes in

0citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Andrew GreenerSchool of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, UK.ORCID https://orcid.org/0000-0001-8098-6276

Stephen P ArgentSchool of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, UK.ORCID https://orcid.org/0000-0002-3461-9675

Coby J ClarkeSchool of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, UK.

Miriam L O'DuillSchool of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, UK.ORCID https://orcid.org/0000-0002-8312-824X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Hypervalent iodine(III) reagents have become indispensable tools in organic synthesis, but gaps remain in the functionalities they can transfer. In this study, a fundamental understanding of the thermal stability of phosphorus-iodonium ylids is obtained through X-ray diffraction, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Insights into the structural factors affecting thermal stability and potential decomposition pathways will enable the future design and development of new reagents.

Indexed as

hypervalent iodinereagent developmentstructural analysisthermal stabilitythermogravimetric analysis

Identifiers

PMID39559440

DOI10.3762/bjoc.20.245

PMCPMC11571945

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.