Evidence map›Paper›PMID 39554858›Full record

ArticleACS materials Au2024

Efficient Microwave Irradiation-Assisted Synthesis of Benzodioxinoquinoxaline and Its Donor-Variegated Derivatives Enabling Long-Lived Emission and Efficient Bipolar Charge Carrier Transport.

Liliia Deva, Mariia Stanitska, Levani Skhirtladze, Amjad Ali, Glib Baryshnikov, Dmytro Volyniuk, Stepan Kutsiy, Mykola Obushak, Monika Cekaviciute, Pavlo Stakhira and 1 more

Abstract read
In one paragraph

Article in ACS materials Au, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Liliia DevaDepartment of Electronic Engineering, Institute of Telecommunications, Radioelectronics and Electronic Engineering, Lviv Polytechnic National University, Stepan Bandera st. 12, Lviv 79013, Ukraine.ORCID https://orcid.org/0000-0003-3814-7721
Mariia StanitskaKaunas University of Technology, Baršausko 59, Kaunas 51423, Lithuania.ORCID https://orcid.org/0000-0003-3904-0686
Levani SkhirtladzeKaunas University of Technology, Baršausko 59, Kaunas 51423, Lithuania.
Amjad AliLaboratory of Organic Electronics, Department of Science and Technology, Linköping University, Norrköping SE-60174, Sweden.
Glib BaryshnikovLaboratory of Organic Electronics, Department of Science and Technology, Linköping University, Norrköping SE-60174, Sweden.ORCID https://orcid.org/0000-0002-0716-3385
Dmytro VolyniukKaunas University of Technology, Baršausko 59, Kaunas 51423, Lithuania.ORCID https://orcid.org/0000-0003-3526-2679
Stepan KutsiyDepartment of Electronic Engineering, Institute of Telecommunications, Radioelectronics and Electronic Engineering, Lviv Polytechnic National University, Stepan Bandera st. 12, Lviv 79013, Ukraine.
Mykola ObushakIvan Franko National University of Lviv, Kyryla i Mefodiya 6, Lviv 79000, Ukraine.ORCID https://orcid.org/0000-0001-8146-9529
Monika CekaviciuteKaunas University of Technology, Baršausko 59, Kaunas 51423, Lithuania.
Pavlo StakhiraDepartment of Electronic Engineering, Institute of Telecommunications, Radioelectronics and Electronic Engineering, Lviv Polytechnic National University, Stepan Bandera st. 12, Lviv 79013, Ukraine.
Juozas Vidas GrazuleviciusKaunas University of Technology, Baršausko 59, Kaunas 51423, Lithuania.ORCID https://orcid.org/0000-0002-4408-9727

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

To enhance the usually low-charge carrier mobilities of highly twisted donor-acceptor-type compounds that exhibit thermally activated delayed fluorescence, we designed a rodlike acceptor benzodioxinoquinoxaline. This acceptor and two donor-acceptor-donor derivatives were synthesized via microwave Buchwald-Hartwig cross-coupling reactions with yields of up to 91%. The compounds exhibit three different types of photoluminescence, which is well-explained by quantum chemical calculations. Benzodioxinoquinoxaline shows blue fluorescence, with a very short lifetime of 0.64 ns. Its derivatives exhibit either green solid-state-enhanced thermally activated delayed fluorescence (SSE-TADF) or room-temperature phosphorescence (RTP) with lifetimes approaching 7 ms. When molecularly dispersed in a polymeric host, the compounds show a photoluminescence quantum yield close to 60%. The derivatives containing acridine or phenoxazine moieties exhibit bipolar charge transport. At an electric field of 5.8 × 10

Identifiers

PMID39554858
PMCPMC11565285

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.