Evidence map›Paper›PMID 39546594›Full record

ArticleScience advances2024

Gas-phase preparation of silylacetylene (SiH

Shane J Goettl, Allen Vincent, Mateus X Silva, Zhenghai Yang, Breno R L Galvão, Rui Sun, Ralf I Kaiser

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Science advances, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Shane J GoettlDepartment of Chemistry, University of Hawai'i at Mānoa, Honolulu, HI 96822, USA.ORCID 0000-0003-1796-5725
Allen VincentDepartment of Chemistry, University of Hawai'i at Mānoa, Honolulu, HI 96822, USA.ORCID 0009-0008-2099-4491
Mateus X SilvaCentro Federal de Educação Tecnológica de Minas Gerais, Belo Horizonte 30421-169, Brazil.ORCID 0000-0001-9629-3829
Zhenghai YangDepartment of Chemistry, University of Hawai'i at Mānoa, Honolulu, HI 96822, USA.ORCID 0009-0001-7586-1425
Breno R L GalvãoCentro Federal de Educação Tecnológica de Minas Gerais, Belo Horizonte 30421-169, Brazil.ORCID 0000-0002-4184-2437
Rui SunDepartment of Chemistry, University of Hawai'i at Mānoa, Honolulu, HI 96822, USA.ORCID 0000-0003-0638-1353
Ralf I KaiserDepartment of Chemistry, University of Hawai'i at Mānoa, Honolulu, HI 96822, USA.ORCID 0000-0002-7233-7206

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Elementary reaction mechanisms constitute a fundamental infrastructure for chemical processes as a whole. However, while these mechanisms are well understood for second-period elements, involving those of the third period and beyond can introduce unorthodox reactivity. Combining crossed molecular beam experiments with electronic structure calculations and molecular dynamics simulations, we provide compelling evidence on an exotic insertion of an unsaturated sigma doublet radical into a silicon-hydrogen bond as observed in the barrierless gas-phase reaction of the D1-ethynyl radical (C

Identifiers

PMID39546594
PMCPMC11566991

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.