ArticleNature communications2024
Synthesis and redox catalysis of Carbodiphosphorane ligated stannylene.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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Who cites it
4 citing papers in PubMed.
- Speciation-Controlled C-F Bond Functionalization Enabled by Zwitterionic Pnictinidenes.Angewandte Chemie (International ed. in English) · 2026Article
- Probing Heterogeneous Catalytic Reactions via Tip-Enhanced Raman Spectroscopy: Recent Progress and Future Perspectives.Chemical & biomedical imaging · 2026Review
- Zwitterionic Heavier Pnictinidenes in Redox Catalysis.Angewandte Chemie (International ed. in English) · 2025Article
- Carbon-Centered Reactivity in Carbodiphosphorane-Based Ligands Allowing for Redox-Non-Innocent Ligand/Ligand Dual Bond-Activation.Angewandte Chemie (International ed. in English) · 2025Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
Heavier group 14 carbene analogues, exhibiting transition-metal-like behavior, display remarkable capability for small molecule activation and coordination chemistry. However, their application in redox catalysis remains elusive. In this paper, we report the synthesis and isolation of a stannylene with carbodiphosphorane ligand. The nucleophilic reactivity at the divalent tin center is elucidated by computational and reactivity studies. Moreover, this stannylene exhibits catalytic activity in the hydrodefluorination reaction of fluoroarenes. Mechanistic investigations into the elementary steps confirm a Sn
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Registered trials
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