ArticleNature communications2024
Phase-transformable metal-organic polyhedra for membrane processing and switchable gas separation.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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Who cites it
4 citing papers in PubMed.
- Polymer-Grafted Cu(II) Metal-Organic Polyhedra as Scalable, Melt-Processable Porous Materials.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Article
- Transferring Porosity Across Physical States Using Metal-Organic Cages: Porous Liquids, Glasses, Rubbers, and More.Angewandte Chemie (International ed. in English) · 2026Review
- Carbazole-Based Thin Microporous Polymer Films for Photocatalytic Hydrogen Evolution.Advanced materials (Deerfield Beach, Fla.) · 2025Article
Corrections and comments
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Authors and funding
15 authors.
Funding
Abstract
The capability of materials to interconvert between different phases provides more possibilities for controlling materials' properties without additional chemical modification. The study of state-changing microporous materials just emerged and mainly involves the liquefication or amorphization of solid adsorbents into liquid or glass phases by adding non-porous components or sacrificing their porosity. The material featuring reversible phases with maintained porosity is, however, still challenging. Here, we synthesize metal-organic polyhedra (MOPs) that interconvert between the liquid-glass-crystal phases. The modular synthetic approach is applied to integrate the core MOP cavity that provides permanent microporosity with tethered polymers that dictate the phase transition. We showcase the processability of this material by fabricating a gas separation membrane featuring tunable permeability and selectivity by switching the state. Compared to most conventional porous membranes, the liquid MOP membrane particularly shows the selectivity for CO
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Registered trials
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