ArticleSmall methods2025
Versatile Organometallic Synthesis of 0D/2D Metal@Germanane Nanoarchitectonics for Electrochemical Energy Conversion Applications.
Article in Small methods, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- 2D Germanane-Based Z-Scheme Heterojunctions for Ultrafast Antibiotic Degradation and Mineralization.Small science · 2026Article
- Molecularly Engineered 2D Xene Heterostructures With Implanted Peroxidase-Like Activity for Mimicking Enzyme Functions.Small methods · 2026Article
- From Inception to Innovation: 20 Years of Nanoarchitectonics.Chemistry, an Asian journal · 2025Review
- Versatile Organometallic Synthesis of 0D/2D Metal@Germanane Nanoarchitectonics for Electrochemical Energy Conversion Applications.Small methods · 2025Article
- Direct Covalent Functionalization of H-Terminated 2D Germanane with Thiolated Molecules: Passivation and Tuning of Optoelectronic Properties.ACS applied materials & interfaces · 2024Article
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Authors and funding
4 authors.
Funding
Abstract
Hydrogen-terminated 2D-Germanane (2D-GeH), a germanium-based 2D material akin to graphene, is receiving enormous attention owing to its predicted optoelectronic characteristics. However, experimental research of 2D-GeH is still in an early stage, and therefore its real implementation for task-specific applications will depend on the correct development of suitable chemical functionalization methods. Herein, a general and straightforward organometallic (OM) approach is provided for the robust functionalization of 2D-GeH with different 0D noble metal nanoparticles (M-NPs), resulting in 0D/2D M@GeH nanoarchitectonics. As a proof-of-principle, 0D/2D Pt@GeH and Au@GeH nanoarchitectonics have been successfully synthesized, characterized, and explored as unconventional electrocatalysts for boosting energy conversion reactions. While the hydrogen evolution reaction activity was evaluated for Pt@GeH, the oxygen reduction reaction was interrogated for Au@GeH. Interestingly, the implanted catalytic features of M-NPs yielded to 0D/2D M@GeH nanoarchitectonics with enhanced energy conversion activity comparing to pristine 2D-GeH counterpart. This work proves the suitability of 2D-GeH as unconventional substrates to stabilize nobleM-NPs, and the versatility of the OM approach for the custom design of a new family of 0D/2D M@GeH nanoarchitectonics to expand the implementation of monoelemental 2D materials as promising electrocatalysts in energy conversion field and beyond.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.