Evidence map›Paper›PMID 39530078›Full record

ArticleBeilstein journal of organic chemistry2024

C-C Coupling in sterically demanding porphyrin environments.

Liam Cribbin, Brendan Twamley, Nicolae Buga, John E O' Brien, Raphael Bühler, Roland A Fischer, Mathias O Senge

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Article in Beilstein journal of organic chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Liam CribbinSchool of Chemistry, Chair of Organic Chemistry, Trinity Biomedical Sciences Institute, 152-160 Pearse Street, Trinity College Dublin, The University of Dublin, Dublin, D02 R590, Ireland.ORCID https://orcid.org/0009-0003-2997-4140
Brendan TwamleySchool of Chemistry, Trinity College Dublin, The University of Dublin, Dublin 2, Ireland.
Nicolae BugaSchool of Chemistry, Chair of Organic Chemistry, Trinity Biomedical Sciences Institute, 152-160 Pearse Street, Trinity College Dublin, The University of Dublin, Dublin, D02 R590, Ireland.ORCID https://orcid.org/0009-0007-2553-0445
John E O' BrienSchool of Chemistry, Trinity College Dublin, The University of Dublin, Dublin 2, Ireland.
Raphael BühlerTUM School of Natural Sciences, Technical University of Munich, Lichtenbergstr. 4, 85748 Garching, Germany.ORCID https://orcid.org/0009-0005-9277-8809
Roland A FischerTUM School of Natural Sciences, Technical University of Munich, Lichtenbergstr. 4, 85748 Garching, Germany.
Mathias O SengeSchool of Chemistry, Chair of Organic Chemistry, Trinity Biomedical Sciences Institute, 152-160 Pearse Street, Trinity College Dublin, The University of Dublin, Dublin, D02 R590, Ireland.ORCID https://orcid.org/0000-0002-7467-1654

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Unlike their planar counterparts, classic synthetic protocols for C-C bond forming reactions on nonplanar porphyrins are underdeveloped. The development of C-C bond forming reactions on nonplanar porphyrins is critical in advancing this field of study for more complex porphyrin architectures, which could be used in supramolecular assemblies, catalysis, or sensing. In this work a library of arm-extended dodecasubstituted porphyrins was synthesized through the optimization of the classic Suzuki-Miyaura coupling of peripheral haloaryl substituents with a range of boronic acids. We report on palladium-catalyzed coupling attempts on the

Indexed as

C–C couplingconformational analysisnonplanar porphyrinPd-catalysisporphyrin

Identifiers

PMID39530078
PMCPMC11552435

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.