ArticleACS omega2024
Probing Ce- and Zr-Fumarate Metal-Organic Framework Formation in Aqueous Solutions with In Situ Raman Spectroscopy and Synchrotron X-ray Diffraction.
Article in ACS omega, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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1 citing paper in PubMed.
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The synthesis of Ce-fumarate and Zr-fumarate metal-organic framework (MOF) is monitored for the first time with in situ Raman spectroscopy in custom-built solvothermal reactors. Several synthesis conditions were explored for Ce-fumarate at room temperature. The use of the method for high-temperature synthesis of Zr-fumarate is also demonstrated. In situ Raman monitoring provided insights into both the solution and crystalline phases of the reaction medium, revealing the dynamic interplay among precursors, modulators, and the forming MOF structure. The reaction kinetics was determined by following the characteristic peak at 1666 cm
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