Evidence map›Paper›PMID 39502183›Full record

ArticleRSC advances2024

Phenylsulfonate as a photolabile group for intramolecular carbon-carbon cross-coupling reactions.

Simon Plaize, Jean-François Morin

Abstract read
In one paragraph

Article in RSC advances, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors.

Simon PlaizeDépartement de Chimie and Centre de Recherche sur les Matériaux Avancés (CERMA), Université Laval 1045 Ave de La Médecine Québec G1V 0A6 Canada jean-francois.morin@chm.ulaval.ca.
Jean-François MorinDépartement de Chimie and Centre de Recherche sur les Matériaux Avancés (CERMA), Université Laval 1045 Ave de La Médecine Québec G1V 0A6 Canada jean-francois.morin@chm.ulaval.ca.ORCID https://orcid.org/0000-0002-9259-9051

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Efficient cyclization reactions play a pivotal role in the synthesis of extended polycyclic aromatic hydrocarbons (PAHs) and graphene nanoribbons. Although efficient reactions have been developed, a simple yet versatile method that is compatible with most functional groups is still lacking. Herein, we report the use of phenylsulfonates as a photolabile group to generate aryl radicals that undergo a radical cyclization reaction to produce triphenylene derivatives. The phenylsulfonate group proves to be a highly adaptable and robust photolabile group, and compatible with Suzuki cross-coupling conditions. Kinetic and optimization experiments have been conducted, shedding light on the potential of this reaction as a versatile tool for the synthesis of PAHs.

Identifiers

PMID39502183
PMCPMC11536975

What OpenQuestion holds

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LicenceCC BY-NC
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.