Evidence map›Paper›PMID 39502177›Full record

ArticleRSC advances2024

Surface science studies of the coverage dependent adsorption of methyl acetate and methyl propanoate on graphite.

Jack E Fulker, Wendy A Brown

Abstract read
In one paragraph

Article in RSC advances, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors.

Jack E FulkerDepartment of Chemistry, University of Sussex Falmer Brighton BN1 9QJ UK w.a.brown@sussex.ac.uk.ORCID https://orcid.org/0009-0009-6668-0428
Wendy A BrownDepartment of Chemistry, University of Sussex Falmer Brighton BN1 9QJ UK w.a.brown@sussex.ac.uk.ORCID https://orcid.org/0000-0001-5934-1270

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Complex organic molecules (COMs) have been detected in a wide range of astrophysical environments, including the interstellar medium, comets and proto-planetary disks. The icy mantles that form on dust grains in these environments are thought to be the chemical nurseries that allow the formation of many of the COMs that have been identified. As such, the adsorption, thermal processing and desorption of COMs from dust grain surfaces are important in understanding the astrochemical networks as a whole. To study these processes, surface science techniques (temperature programmed desorption (TPD) and reflection absorption infrared spectroscopy (RAIRS)) have been used to investigate ices of the simple esters, methyl acetate and methyl propanoate, adsorbed on a graphitic dust grain analogue surface (highly oriented pyrolytic graphite, HOPG) at 28 K. From the TPD experiments, kinetic parameters have been determined for the desorption of the esters from graphite. The data show a clear coverage dependence for the desorption energies and pre-exponential factors in the sub-monolayer regime. For methyl acetate, the desorption energies and pre-exponential factors range from 57.1 ± 0.4 to 47.2 ± 0.3 kJ mol

Identifiers

PMID39502177
PMCPMC11537193

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.