Evidence map›Paper›PMID 39501593›Full record

ArticleMacromolecular rapid communications2025

Uniform Polymer Microspheres by Photoinduced Metal-Free Atom Transfer Radical Precipitation Polymerization.

Tugrul Cem Bicak, Huiyin Liu, Karsten Haupt, Carlo Gonzato, Jérôme Fresnais, Christine Ménager, Louis Fensterbank, Cyril Ollivier, Nébéwia Griffete

Abstract read
In one paragraph

Article in Macromolecular rapid communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Review
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Tugrul Cem BicakPhysico-chimie des Électrolytes et Nanosystèmes Interfaciaux, PHENIX, Sorbonne Université CNRS, Paris, F-75005, France.
Huiyin LiuPhysico-chimie des Électrolytes et Nanosystèmes Interfaciaux, PHENIX, Sorbonne Université CNRS, Paris, F-75005, France.
Karsten HauptCNRS Enzyme and Cell Engineering Laboratory, Université deTechnologie de Compiègne, Rue du Docteur Schweitzer, CS 60319, Compiègne, 60203, France.
Carlo GonzatoCNRS Enzyme and Cell Engineering Laboratory, Université deTechnologie de Compiègne, Rue du Docteur Schweitzer, CS 60319, Compiègne, 60203, France.
Jérôme FresnaisPhysico-chimie des Électrolytes et Nanosystèmes Interfaciaux, PHENIX, Sorbonne Université CNRS, Paris, F-75005, France.
Christine MénagerPhysico-chimie des Électrolytes et Nanosystèmes Interfaciaux, PHENIX, Sorbonne Université CNRS, Paris, F-75005, France.
Louis FensterbankSorbonne Université, CNRS, Institut Parisien de Chimie Moléculaire, 4 Place Jussieu, CC 229, F-75252, Paris, Cedex 05, France.
Cyril OllivierSorbonne Université, CNRS, Institut Parisien de Chimie Moléculaire, 4 Place Jussieu, CC 229, F-75252, Paris, Cedex 05, France.
Nébéwia GriffetePhysico-chimie des Électrolytes et Nanosystèmes Interfaciaux, PHENIX, Sorbonne Université CNRS, Paris, F-75005, France.ORCID https://orcid.org/0000-0003-4888-6261

Funding

Emergence Sorbonne Université and Initiatives Sciences et Ingénierie Moléculaire de l'Alliance Sorbonne UniversitéSorbonne Université, CNRS, and Region Ile de France
6 · The paper itself

Abstract

Herein, a photoinduced method is introduced for the synthesis of highly cross-linked and uniform polymer microspheres by atom transfer radical polymerization (ATRP) at room temperature and in the absence of stabilizers or surfactants. Uniform particles are obtained at monomer concentrations as high as 10% (by volume), with polymers being exempt from contamination by residual transition metal catalysts, thereby overcoming the two major longstanding problems associated with thermally initiated ATRP-mediated precipitation polymerization. Moreover, the obtained particles have also immobilized ATRP initiators on their surface, which directly enables the controlled growth of densely grafted polymer layers with adjustable thickness and a well-defined chemical composition. The method is then employed successfully for the synthesis of molecularly imprinted polymer microspheres.

Indexed as

MicrospheresPolymerizationPolymersCatalysisFree RadicalsMetalsParticle SizePhotochemical ProcessesSurface PropertiesFree RadicalsMetalsPolymersmolecularly imprinted polymerphotoinduced metal‐free ATRPpoly(divinylbenzene)polymer microsphereprecipitation polymerizationuniform

Identifiers

PMID39501593
PMCPMC11713857

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.