Evidence map›Paper›PMID 39494629›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2024

Oxygen Defect Site Filling Strategy Induced Moderate Enrichment of Reactants for Efficient Electrocatalytic Biomass Upgrading.

Baixue Cheng, Haoyu Zhan, Yankun Lu, Danning Xing, Xingshuai Lv, Thomas Frauenheim, Peng Zhou, Shuangyin Wang, Yuqin Zou

Abstract read
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In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Review
  2. Review
  3. Review
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Baixue ChengState Key Laboratory of Bio-fibers and ECo─textiles, College of Materials Science and Engineering, Collaborative Innovation Center of Shandong Marine Biobased Fibers and Ecological Textiles, Institute of Marine Biobased Materials, Qingdao University, Qingdao, 266071, P. R. China.
Haoyu ZhanState Key Laboratory of Bio-fibers and ECo─textiles, College of Materials Science and Engineering, Collaborative Innovation Center of Shandong Marine Biobased Fibers and Ecological Textiles, Institute of Marine Biobased Materials, Qingdao University, Qingdao, 266071, P. R. China.
Yankun LuState Key Laboratory of Bio-fibers and ECo─textiles, College of Materials Science and Engineering, Collaborative Innovation Center of Shandong Marine Biobased Fibers and Ecological Textiles, Institute of Marine Biobased Materials, Qingdao University, Qingdao, 266071, P. R. China.
Danning XingShandong Institute of Advanced Technology, Jinan, 250100, P. R. China.
Xingshuai LvCollege of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, 266100, P. R. China.
Thomas FrauenheimSchool of Science, Constructor University, 28759, Bremen, Germany.
Peng ZhouState Key Laboratory of Bio-fibers and ECo─textiles, College of Materials Science and Engineering, Collaborative Innovation Center of Shandong Marine Biobased Fibers and Ecological Textiles, Institute of Marine Biobased Materials, Qingdao University, Qingdao, 266071, P. R. China.
Shuangyin WangState Key Laboratory of Chemo/Bio-Sensing and Chemometrics, College of Chemistry and Chemical Engineering, Advanced Catalytic Engineering Research Center of the Ministry of Education, Hunan University, Changsha, 410082, P. R. China.
Yuqin ZouState Key Laboratory of Chemo/Bio-Sensing and Chemometrics, College of Chemistry and Chemical Engineering, Advanced Catalytic Engineering Research Center of the Ministry of Education, Hunan University, Changsha, 410082, P. R. China.ORCID https://orcid.org/0000-0003-3038-1521

Funding

National Key R&D Program of China 2023YFA1507400National Natural Science Foundation of China 21825201National Natural Science Foundation of China 22122901Natural Science Foundation of Shandong Province ZR202111240183Natural Science Foundation of Shandong Province ZR2021QF120Natural Science Foundation of Shandong Province ZR2023QB235Provincial Natural Science Foundation of Hunan 2021JC0008Provincial Natural Science Foundation of Hunan 2021RC3054
6 · The paper itself

Abstract

The electrocatalytic oxidation of 5-hydroxymethylfurfural (HMF) provides a feasible approach for the efficient utilization of biomass. Defect regulation is an effective strategy in the field of biomass upgrading to enhance the adsorption capacity of reactants and thus increase the activity. However, how to select appropriate strategies to regulate the over-enrichment of reactants induced by excessive oxygen vacancy is still a huge challenge. In this work, the defect-filling strategy to design and construct an element-filled oxygen vacancy site layered double hydroxide (S─Ov─LDH) is adopted, which achieves a significant reduction in the electrolysis potential of biomass platform molecule HMF oxidation reaction and a significant increase in current density. Physical characterizations, electrochemical measurements, and theoretical calculations prove that the formation of metal─S bond in the second shell effectively regulates the electronic structure of the material, thus weakening the over-strong adsorption of HMF and OH

Indexed as

biomass upgradingdefect filling strategyelectrocatalysislayered double hydroxidesmoderate adsorptions

Identifiers

PMID39494629
PMCPMC11672306

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.