Evidence map›Paper›PMID 39477927›Full record

ArticleNature communications2024

Water-promoted oxidative coupling of aromatics with subnanometer palladium clusters confined in zeolites.

Yunchao Feng, Hongtao Wang, Tianxiang Chen, Miguel Lopez-Haro, Feng He, Zhe He, Carlo Marini, Benedict Tsz Woon Lo, Lichen Liu

Abstract read
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. CuMolecules (Basel, Switzerland) · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Yunchao FengDepartment of Chemistry, Engineering Research Center of Advanced Rare Earth Materials, Tsinghua University, 100084, Beijing, China.ORCID http://orcid.org/0009-0008-1331-7521
Hongtao WangDepartment of Chemistry, Engineering Research Center of Advanced Rare Earth Materials, Tsinghua University, 100084, Beijing, China.
Tianxiang ChenDepartment of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, 999077, Kowloon, Hong Kong, China.ORCID http://orcid.org/0000-0002-1578-0957
Miguel Lopez-HaroDepartamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, Facultad de Ciencias, Universidad de Cádiz, Puerto Real, 11510, Spain.ORCID http://orcid.org/0000-0003-2560-8015
Feng HeDepartment of Chemistry, Engineering Research Center of Advanced Rare Earth Materials, Tsinghua University, 100084, Beijing, China.
Zhe HeDepartment of Chemistry, Engineering Research Center of Advanced Rare Earth Materials, Tsinghua University, 100084, Beijing, China.
Carlo MariniALBA Synchrotron Light Source, Cerdanyola del Vallès, Barcelona, 08290, Spain.
Benedict Tsz Woon LoDepartment of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, 999077, Kowloon, Hong Kong, China.ORCID http://orcid.org/0000-0002-4853-0196
Lichen LiuDepartment of Chemistry, Engineering Research Center of Advanced Rare Earth Materials, Tsinghua University, 100084, Beijing, China. lichenliu@mail.tsinghua.edu.cn.ORCID http://orcid.org/0000-0001-5067-0481

Funding

National Natural Science Foundation of China (National Science Foundation of China) 22272087
6 · The paper itself

Abstract

A fundamental understanding of the active sites in working catalysts can guide the rational design of new catalysts with improved performances. In this work, we have followed the evolution of homogeneous and heterogeneous Pd catalysts under the reaction conditions for aerobic oxidative coupling of toluene for the production of 4,4'-bitolyl. We have found that subnanometer Pd clusters made with a few Pd atoms are the working active sites in both homogeneous and heterogeneous catalytic systems. Moreover, water can promote the activity of Pd clusters by nearly one-order magnitude for oxidative coupling reaction by facilitating the activation of O

Identifiers

PMID39477927
PMCPMC11525991

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.