ArticleMolecules (Basel, Switzerland)2024
Sub-10 nm PdNi@PtNi Core-Shell Nanoalloys for Efficient Ethanol Electro-Oxidation.
Article in Molecules (Basel, Switzerland), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Oxidation-Induced Internal Chemical Patterning in Copper-Gold Nanoalloys.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Hydrogen spillover as an interfacial strategy for nitrate electroreduction to ammonia.Chemical science · 2026Review
- Latest Progress in Pd-Based Metallenes: From Formation Mechanism, Structural Design, Optimization Strategies to Electrocatalytic Applications.ACS omega · 2026Review
- Nanoflower-like CuCoMaterials (Basel, Switzerland) · 2026Article
- Nanostructured Catalysts for Electro- and Photocatalytic Energy Conversion: Design Strategies, Mechanistic Descriptors, and Practical Applications.Nanomaterials (Basel, Switzerland) · 2026Review
- Development of Nanomaterials for Energy and Environmental Applications.Molecules (Basel, Switzerland) · 2025Article
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2 authors.
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Abstract
By controlling the structure and composition of Pt-based nanoalloys, the ethanol oxidation reaction (EOR) performances of Pt alloy catalysts can be effectively improved. Herein, we successfully synthesis sub-10 nm PdNi@PtNi nanoparticles (PdNi@PtNi NPs) with a core-shell structure by a one-pot method. The sub 10 nm core-shell nanoparticles possess more effective atoms and exhibit a synergistic effect which can lead to a shift in the d-band center and alter binding energies toward adsorbates. Due to the synergistic effect and unique core-shell structure, the PdNi@PtNi NP catalysts exhibit excellent electrocatalytic performance for ethanol oxidation reactions in alkaline, achieving 9.30 times more mass activity and 7.05 times more specific activity that of the state-of-the-art Pt/C catalysts. Moreover, the stability of PdNi@PtNi NPs was also greatly improved over PtNi nanoparticles, PtPd nanoparticles, and commercial Pt/C. This strategy provides a new idea for improving the electrocatalytic performance of Pt-based catalysts for EORs.
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