ArticlePolymers2024
The Synthesis of a New Glycoluryl-Melamine-Formaldehyde Polymer under the Action of HEDP and the Investigation of the Content of Methylol Groups and Free Formaldehyde.
Article in Polymers, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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11 authors.
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Abstract
This study outlines a method for preparing a complex involving glycoluril and melamine (GU-ME). The structure of the resultant complex was analyzed using IR and NMR spectroscopy. In the subsequent phase, the polymer GUMEFA was derived from the resultant complex, employing hydroxyethylidene diphosphonic acid (HEDP) as a sustainable plasticizer, with a proposed chemical mechanism for its formation. The molecular weight of the resulting GUMEFA was analyzed, and the formation chemistry was proposed. GUMEFA was characterized, and its free formaldehyde and methylol group contents were investigated. It was observed that GUMEFA prepared with HEDP contained approximately 1.15-1.34 wt.% free formaldehyde and 1.56-0.54 wt.% methylol groups. These findings provide valuable insights for developing resins of different compositions and applications, thereby paving the way for producing composite materials with tailored properties.
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