ArticleAngewandte Chemie (International ed. in English)2025
Redox Self-Equilibration in Molecular Vanadium Oxide Mixtures Enables Multi-Electron Storage.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Revisiting the Robin-Day Classification through Switchable Electronic States in Multimetallic Vanadium Oxides.Journal of the American Chemical Society · 2026Article
- Multiredox Polyoxovanadate-Based Ionic Liquids for Nonaqueous Redox Flow Batteries.ChemSusChem · 2026Article
- Redox Self-Equilibration in Molecular Vanadium Oxide Mixtures Enables Multi-Electron Storage.Angewandte Chemie (International ed. in English) · 2025Article
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Authors and funding
10 authors.
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Abstract
Polyoxometalates (POMs) are ideal components for reversible multi-electron storage in energy technologies. To-date, most redox-applications employ only single, individual POM species, which limits the number of electrons that can be stored within a given potential window. Here, we report that spontaneous redox self-equilibration during cluster synthesis leads to the formation of two structurally related polyoxovanadates which subsequently aggregate into co-crystals. This results in systems with significantly increased redox reactivity. The mixed POM system was formed by non-aqueous self-assembly of a vanadate precursor in the presence of Mg
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