ArticleChemistry (Weinheim an der Bergstrasse, Germany)2024
Emergent Behavior of a Photoswitchable Solute in a Biphasic Solvent System.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
2 citing papers in PubMed.
- A Versatile Strategy for Light-Driven Active Transport of Ions.Angewandte Chemie (International ed. in English) · 2026Article
- Emergent Behavior of a Photoswitchable Solute in a Biphasic Solvent System.Chemistry (Weinheim an der Bergstrasse, Germany) · 2024Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
2 authors.
Funding
Abstract
Due to thermal E/Z isomerization, hydrazones in solution typically exist in thermodynamic equilibria between their isomers. Irradiation of such solutions leads to photostationary states that may differ from the equilibrium distribution. Operating such switchable hydrazones in a biphasic system of two immiscible solvents introduces three new degrees of freedom: the E/Z equilibrium in the second solvent and two equilibria for distribution of each of the isomers between the solvents. Irradiation of such a system can be performed in three different ways - the first solvent only, the second solvent only, and both solvents at once - all yielding distinct outcomes. Depending on the choice of materials and the mode of irradiation, such setup may lead to different emergent behaviors that are not immediately intuitive, including net cyclic transport or the accumulation of one photoswitched product in one of the phases, beyond what is reachable by irradiating a simple solution of the same photoswitch.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.