ArticleNature communications2024
Restructuring the interfacial active sites to generalize the volcano curves for platinum-cobalt synergistic catalysis.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Potential-Dependent Reversible Restructuring of Pt-Au Alloy Electrocatalysts.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Hydrogen generation promoted by single-atom-based thermochemical catalysts.Nature reviews. Chemistry · 2026Review
- Multi-field coupling enhanced plasmonic MoNature communications · 2026Article
- Direct approach to high-resolution, square-lattice alternating nanodot array by breaking hexagonal symmetry of block copolymer spheres.Science advances · 2025Article
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Authors and funding
17 authors.
Funding
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Abstract
Computationally derived volcano curve has become the gold standard in catalysis, whose practical application usually relies on empirical interpretations of composition or size effects by the identical active site assumption. Here, we present a proof-of-concept study on disclosing both the support- and adsorbate-induced restructuring of Pt-Co bimetallic catalysts, and the related interplays among different interfacial sites to propose the synergy-dependent volcano curves. Multiple characterizations, isotopic kinetic investigations, and multiscale simulations unravel that the progressive incorporation of Co into Pt catalysts, driven by strong Pt-C bonding (metal-support interfaces) and Co-O bonding (metal-adsorbate interfaces), initiates the formation of Pt-rich alloys accompanied by isolated Co species, then Co segregation to epitaxial CoO
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