Optical and Structural Properties of Anisotropic ZnS Nanoparticle Suspensions.

Naama Gatenio, Sofiya Kolusheva, William Chèvremont, Shachar Moskovich, Dhanush Patil, Kenan Song, Yuval Golan

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Article in Langmuir : the ACS journal of surfaces and colloids, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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4 · The record

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5 · Who and what money

Authors and funding

7 authors.

Naama GatenioDepartment of Materials Engineering, Ben-Gurion University of the Negev, Beer-Sheva 8410501, Israel.

Sofiya KolushevaIlse Katz Institute for Nanoscale Science and Technology, Ben-Gurion University of the Negev, Beer-Sheva 8410501, Israel.

William ChèvremontESRF - The European Synchrotron, 71 avenue des Martyrs, CS40220, 38043 Grenoble Cedex 9,France.

Shachar MoskovichDepartment of Materials Engineering, Ben-Gurion University of the Negev, Beer-Sheva 8410501, Israel.

Dhanush PatilSchool of Environmental, Civil, Agricultural, and Mechanical Engineering (ECAM), College of Engineering, University of Georgia, Athens, Georgia 30602, United States.

Kenan SongSchool of Environmental, Civil, Agricultural, and Mechanical Engineering (ECAM), College of Engineering, University of Georgia, Athens, Georgia 30602, United States.ORCID 0000-0002-0447-2449

Yuval GolanDepartment of Materials Engineering, Ben-Gurion University of the Negev, Beer-Sheva 8410501, Israel.ORCID 0000-0003-1369-0285

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We studied the optical and structural properties of highly ordered arrays of surfactant-capped ZnS nanowires (NWs) and nanorods (NRs) in organic suspensions. The photoluminescence (PL) emission measured under different concentrations and postsynthesis washing cycles interestingly showed increasing emission upon decreasing nanoparticle (NP) concentration. Synchrotron small angle X-ray scattering measurements elucidated the liquid-crystal-like structure of the NPs in suspension under different concentrations and temperatures. The NWs are stacked in a simple structure with a hexagonal cross-section, whereas the structure of the NRs is more complex, resembling a smectic-c liquid crystal, and shows unusual thermal expansion versus temperature. The results point out that a certain amount of bound surfactant must be present on the NP surface to maximize the PL intensity.

Identifiers

PMID39413768

DOI10.1021/acs.langmuir.4c03164

PMCPMC11526353

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