Establishing Composition of Solid Solution Based on Single Crystal and Powder X-ray Measurement: The Case of Halogenated Bismuth(III) Complexes with Acetophenone-4-methyl-3-thiosemicarbazone.

Anita M Grześkiewicz, Grzegorz Dutkiewicz, Ibrahim I Ozturk, Maciej Kubicki

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Article in International journal of molecular sciences, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

Authors and funding

4 authors.

Anita M GrześkiewiczFaculty of Chemistry, Adam Mickiewicz University, 61-614 Poznań, Poland.ORCID 0000-0003-0377-2260

Grzegorz DutkiewiczFaculty of Chemistry, Adam Mickiewicz University, 61-614 Poznań, Poland.ORCID 0000-0001-9124-3654

Ibrahim I OzturkSection of Inorganic Chemistry, Department of Chemistry, Tekirdag Namık Kemal University, Tekirdag 59030, Türkiye.ORCID 0000-0003-3164-0038

Maciej KubickiFaculty of Chemistry, Adam Mickiewicz University, 61-614 Poznań, Poland.ORCID 0000-0001-7202-9169

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

New bismuth (III) complexes with acetophenone-4-methyl-3-thiosemicarbazone (L) and halogens (Cl and Br) in both bridging and terminal positions have been synthesized and structurally characterized using single-crystal X-ray diffraction. The pure complexes (Cl or Br) were found to be highly isostructural, which motivated our attempts to create solid solutions of these complexes. A series of such compounds was prepared using various procedures and stoichiometries. A method for determining the mutual concentrations of different halogens, based on the positions of selected peaks in powder diffraction patterns, was tested and compared with other methods.

Indexed as

BismuthCoordination ComplexesThiosemicarbazonesAcetophenonesCrystallography, X-RayHalogenationModels, MolecularMolecular StructurePowder DiffractionX-Ray DiffractionAcetophenonesBismuthCoordination ComplexesThiosemicarbazonesBi complexessolid solutionsVegard’s ruleX-ray diffraction (XRD)

Identifiers

PMID39409141

DOI10.3390/ijms251910814

PMCPMC11477303

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