Study of the Optical and Acoustic Parameters and Surface Tensions of 3,4,4'-Trichlorodiphenylurea in Binary Mixtures with Different Organic Solvents between (293.15 and 323.15) K.

Florinela Sirbu, Alina Catrinel Ion, Ion Ion

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Article in Molecules (Basel, Switzerland), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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3 authors.

Florinela Sirbu"Ilie Murgulescu" Institute of Physical Chemistry of Romanian Academy, Department of Chemical Thermodynamics, 202 Splaiul Independentei Str., 060021 Bucharest, Romania.

Alina Catrinel IonDepartment of Analytical Chemistry and Environmental Engineering, Faculty of Chemical Engineering and Biotechnologies, National University of Science and Technology POLITEHNICA Bucharest, 1-7 Polizu Str., 011061 Bucharest, Romania.

Ion IonDepartment of Analytical Chemistry and Environmental Engineering, Faculty of Chemical Engineering and Biotechnologies, National University of Science and Technology POLITEHNICA Bucharest, 1-7 Polizu Str., 011061 Bucharest, Romania.

Funding

INFRANONOCHEM Nr. 19/01.03.2009,

6 · The paper itself

Abstract

In the present investigations, the density, refractive index and speed of sound for pure organic solvents and binary liquid mixtures of 3,4,4'-Trichlorodiphenylurea between (293.15 and 323.15) K temperatures have been measured up to the solubility limit. From these experimental results, the acoustic impedance, the isentropic compressibility coefficient, the space-filling factor, the specific refraction, the relaxation strength, the intermolecular free length, the surface tension, the solubility and the solvation number of triclocarban in six organic solvents, namely ethyl alcohol, n-Propyl alcohol, n-Butyl alcohol, Tetrahydrofuran, N,N-Dimethylformamide and N,N-Dimethylacetamide have been computed. The studied acoustic and optical parameters and surface tension behavior versus temperature in pure solvents and binary mixtures were useful in understanding the nature and the extent of interaction between the solute and solvent molecules. The results also show the presence of higher degree of interaction between triclocarban and nitrogen-containing solvents in comparison with other solvents. The distribution of triclocarban in water/organic solvent mixtures is frequently encountered in wastewater treatment plants.

Indexed as

3,4,4′-Trichlorodiphenylurealiquid mixturesorganic solventsphysicochemical propertiessolvation numbersurface tension

Identifiers

PMID39407451

DOI10.3390/molecules29194521

PMCPMC11477502

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