ArticleThe journal of physical chemistry letters2024
Efficient Molecular Rectification in Metal-Molecules-Semimetal Junctions.
Article in The journal of physical chemistry letters, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Molecular Rectification: Mechanisms, Modulation Strategies, and Device Realization.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- Tuning of Thermopower in Molecular Junctions by Molecularly Controlled Sculpting of the Density of States in Their Leads.Nano letters · 2026Article
- Unusually High Thermopower in Molecular Junctions from Molecularly Induced Quantized States in Their Semimetal Leads.Nano letters · 2025Article
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Authors and funding
4 authors.
Funding
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Abstract
Molecular rectification is expected to be observed in metal-molecule-metal tunnel junctions in which the resonance levels responsible for their transport properties are spatially localized asymmetrically with respect to the leads. Yet, effects such as electrostatic screening and formation of metal induced gap states reduce the magnitude of rectification that can be realized in such junctions. Here we suggest that junctions of the form metal-molecule(s)-semimetal mitigate these interfacial effects. We report current rectification in junctions based on the semimetal bismuth (Bi) with high rectification ratios (>10
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