ArticleChemSusChem2025
Metal-Free C-X Functionalization in Solid-State via Photochemistry in Ball Mills.
Article in ChemSusChem, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
6 citing papers in PubMed.
- Silent Partners in the Mill: Unveiling the Role of Additives in Mechanochemical Synthesis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Review
- Shaking Up Photochemistry: The Future Frontiers of Mechanophotocatalysis.ACS central science · 2026Review
- One-Step Thermo-Mechanochemical Syntheses of Metal Phthalocyanines and Polyphthalocyanines.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Solid-State Photochemistry in Resonant Acoustic Mixers.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
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Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
We report the first metal- and catalyst-free protocol for the facile cross-coupling of aryl halides towards C-B, C-P and C-S bonds under solid-state ball milling conditions via UV light irradiation. The reactions can be performed in the absence of bulk solvents at room temperature in a mixer mill, yielding up to 99 % and being tolerant towards various functionalized aryl halides (X=I or Br). Furthermore, we developed a novel photoreactor design increasing the light intensity. With this we could demonstrate that our protocol surpasses classical solvent based as well as purely mechanochemical approaches in terms of green metrics and energy efficiency.
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Registered trials
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