Evidence map›Paper›PMID 39394817›Full record

ArticleSmall methods2025

Faster and Safer "In situ" Synthesis of Germanane and Silicane.

Yiannis Georgantas, Theodosis Giousis, Francis P Moissinac, Gareth R Tainton, Sarah J Haigh, Mark A Bissett

Abstract read
In one paragraph

Article in Small methods, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Yiannis GeorgantasDepartment of Materials, Henry Royce Institute, National Graphene Institute, University of Manchester, Ox-ford Road, Manchester, M139PL, UK.ORCID https://orcid.org/0000-0002-0012-3700
Theodosis GiousisDepartment of Materials Science & Engineering, University of Ioannina, Ioannina, 45110, Greece.ORCID https://orcid.org/0000-0003-0164-5647
Francis P MoissinacDepartment of Materials, Henry Royce Institute, National Graphene Institute, University of Manchester, Ox-ford Road, Manchester, M139PL, UK.ORCID https://orcid.org/0000-0002-0143-4762
Gareth R TaintonDepartment of Materials, Henry Royce Institute, National Graphene Institute, University of Manchester, Ox-ford Road, Manchester, M139PL, UK.ORCID https://orcid.org/0000-0002-7072-4640
Sarah J HaighDepartment of Materials, Henry Royce Institute, National Graphene Institute, University of Manchester, Ox-ford Road, Manchester, M139PL, UK.ORCID https://orcid.org/0000-0001-5509-6706
Mark A BissettDepartment of Materials, Henry Royce Institute, National Graphene Institute, University of Manchester, Ox-ford Road, Manchester, M139PL, UK.ORCID https://orcid.org/0000-0002-8908-7960

Funding

Engineering and Physical Sciences Research Council EP/L01548X/1Engineering and Physical Sciences Research Council EP/S021531/1H2020 European Research Council ERC-2016-STG-EvoluTEM-715502Henry Royce Institute and the National Graphene InstituteHenry Royce Institute for Advanced Materials EP/P025021/1Henry Royce Institute for Advanced Materials EP/P025498/1Henry Royce Institute for Advanced Materials EP/R00661X/1Henry Royce Institute for Advanced Materials EP/S019367/1
6 · The paper itself

Abstract

Germanane (GeH) and silicane (SiH), members of the Xanes family, have garnered significant attention as 2D materials due to their diverse properties, which hold promise for applications in electronics, optoelectronics, energy storage, and sensing. Typically, highly concentrated hydrochloric acid (HCl) or hydrofluoric acid (HF) is employed in the synthesis of these Xanes, but both routes are problematic due to slow kinetics and safety concerns, respectively. Here for the first time, a faster and safer method is demonstrated for Xanes synthesis that harnesses the generation of HF "in situ" using a solution of HCl and lithium fluoride (LiF) salt, overcoming the key challenges of the conventional methods. A variety of characterization techniques to establish a baseline is utilized for both Xanes and to provide a holistic knowledge regarding this method, the possible consequences of this approach, and the possibility of applying it to other layered Zintl phases. The novel synthesis protocol results in high-quality GeH and SiH with bandgaps (E

Indexed as

2D materialsgermanane“in situ” HFsilicanesynthesisXanes

Identifiers

PMID39394817
PMCPMC11926497

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.