Biobased Chemicals from d-Galactose: An Efficient Route to 5-Hydroxymethylfurfural Using a Water/MIBK System in Combination with an HCl/AlCl

Angela Martina, Henk H van de Bovenkamp, Jozef G M Winkelman, Inge W Noordergraaf, Francesco Picchioni, Hero J Heeres

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Article in ACS omega, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed

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1 · What the graph read from it

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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

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3 · Its place in the literature

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5 · Who and what money

Authors and funding

6 authors.

Angela MartinaDepartment of Chemical Engineering, Parahyangan Catholic University, Ciumbuleuit 94, Bandung 40141, Indonesia.

Henk H van de BovenkampDepartment of Chemical Engineering (ENTEG), University of Groningen, Nijenborgh 4, Groningen, AG 9747, The Netherlands.

Jozef G M WinkelmanDepartment of Chemical Engineering (ENTEG), University of Groningen, Nijenborgh 4, Groningen, AG 9747, The Netherlands.ORCID https://orcid.org/0000-0001-7888-1731

Inge W NoordergraafDepartment of Chemical Engineering (ENTEG), University of Groningen, Nijenborgh 4, Groningen, AG 9747, The Netherlands.

Francesco PicchioniDepartment of Chemical Engineering (ENTEG), University of Groningen, Nijenborgh 4, Groningen, AG 9747, The Netherlands.ORCID https://orcid.org/0000-0002-8232-2083

Hero J HeeresDepartment of Chemical Engineering (ENTEG), University of Groningen, Nijenborgh 4, Groningen, AG 9747, The Netherlands.ORCID https://orcid.org/0000-0002-1249-543X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

5-Hydroxymethylfurfural (HMF) is an attractive building block for biobased chemicals. Typically, ketoses like d-fructose (FRC) are suitable starting materials and give good yields of HMF in a simple aqueous phase process with a Bro̷nsted acid catalyst. With aldoses, such as d-glucose (GLU), much lower yields were reported in the literature. Here, we report an experimental and modeling study on the use of d-galactose (GAL) for HMF synthesis, using a liquid-liquid system (water/MIBK) in combination with an HCl/AlCl

Identifiers

PMID39372015

DOI10.1021/acsomega.4c02242

PMCPMC11447810

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LicenceCC BY-NC-ND

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.