ArticleACS omega2024
Enhancing Ultradeep Hydrodesulfurization of Coker Diesel through Adsorptive Predenitrogenation.
Article in ACS omega, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Authors and funding
6 authors.
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Abstract
The petroleum refining industry places significant challenge in the production of ultralow-sulfur diesel (ULSD) from various middle distillates with high nitrogen concentration in an energy-efficient and cost-effective way to meet strict environmental regulations as coexisting nitrogen compounds significantly inhibit the ultradeep hydrodesulfurization (HDS). Among all of the approaches reported in the literature for this challenge, a combination of adsorptive denitrogenation (ADN) and HDS has attracted great attention. This study focuses on ultradeep HDS of coker diesel (CD) through a synergistic approach combining ADN over a carbon-based adsorbent and the current HDS process. The study found that the predenitrogenation significantly enhanced the HDS reactivity of CD and greatly reduced the start of run temperature for producing ULSD by even 20 °C, depending on the denitrogenation depth. It results in dominantly decreasing energy and H
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