ArticleChemistry (Weinheim an der Bergstrasse, Germany)2024
Dehydrogenative Coupling Reactions with Guanidino-Functionalized Aromatics.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Cross-Dehydrogenative Coupling Reactions With Redox-Active Guanidine Reagents.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Hydroquinone Oxidation by Redox-active Guanidines and Thioguanidines: Faster Conversion to High-Potential Than to Low-Potential Quinones.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Triggering and Preventing Cyclization of o-Amino-Guanidinobenzenes to 2-Amino-Benzimidazoles.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Fine Tuning of the Redox-Active Diguanidine Ligand in Cationic Cobalt Complexes for Electronic Structure Control.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Dehydrogenative Coupling Reactions with Guanidino-Functionalized Aromatics.Chemistry (Weinheim an der Bergstrasse, Germany) · 2024Article
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Authors and funding
6 authors.
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Abstract
Dehydrogenative coupling (DC) reactions are of importance for the construction of new carbon-element bonds in synthetic organic chemistry. In this work, we report on the synthesis and characterization of several redox-active guanidino-functionalized aromatic molecules (GFAs) for use in DC (C-C and C-O) reactions. In a systematic approach, we first characterize the new DC reagents in all relevant redox and protonation states, and compare their performance in competitive test proton-coupled electron transfer (PCET) reactions. Then, their use in four different DC reactions with different mechanisms is evaluated.
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