Evidence map›Paper›PMID 39367064›Full record

ArticleNature chemistry2024

Multi-stage and multi-colour liquid crystal reflections using a chiral triptycene photoswitchable dopant.

Indu Bala, Joshua T Plank, Brandon Balamut, Drake Henry, Alexander R Lippert, Ivan Aprahamian

Abstract read
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Article in Nature chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.

0numbers the graph read from it
0cells of the map it votes in
14citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

14 citing papers in PubMed.

  1. Dihydrobenzofuro[3,2-Chemical science · 2026
    Article
  2. Mechanically Interlocked Indigo Photoswitches.Angewandte Chemie (International ed. in English) · 2026
    Article
  3. Article
  4. Article
  5. Article
  6. Journal of the American Chemical Society · 2026
    Article
  7. Article
  8. Article
  9. Article
  10. Article
  11. Alternating Orthogonal Switching in a Thiophenyl-Phenyl-Bis-Azobenzene Switch.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025
    Article
  12. Molecular Steganography Using Multistate Photoswitchable Hydrazones.Journal of the American Chemical Society · 2025
    Article
  13. Article
  14. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Indu BalaDepartment of Chemistry, Dartmouth College, Hanover, NH, USA.
Joshua T PlankDepartment of Chemistry, Southern Methodist University, Dallas, TX, USA.
Brandon BalamutDepartment of Chemistry, Dartmouth College, Hanover, NH, USA.
Drake HenryDepartment of Chemistry, Southern Methodist University, Dallas, TX, USA.ORCID http://orcid.org/0009-0008-7171-5819
Alexander R LippertDepartment of Chemistry, Southern Methodist University, Dallas, TX, USA.
Ivan AprahamianDepartment of Chemistry, Dartmouth College, Hanover, NH, USA. ivan.aprahamian@dartmouth.edu.ORCID http://orcid.org/0000-0003-2399-8208

Funding

National Science Foundation (NSF) 2104464Welch Foundation N-2038-202004010
6 · The paper itself

Abstract

The photomodulation of the helical pitch of cholesteric liquid crystals results in dynamic and coloured canvases that can potentially be used in applications ranging from energy-efficient displays to colour filters, anti-counterfeiting tags and liquid crystal (LC) lasers. Here we report on the analysis of a series of photoswitchable chiral dopants that combine the large geometrical change and bistability of hydrazone switches with the efficient helical pitch induction of the chiral motif, triptycene. We elucidate the effects that conformational flexibility, dispersion forces and π-π interactions have on the chirality transfer ability of the dopant. We then use the irradiation time with visible light (442 nm) combined with a simple digital light processing microscope projection set-up to draw numerous stable multi-coloured images on an LC canvas, showcasing the fine control this dopant yields over the LC assembly.

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.