Evidence map›Paper›PMID 39367063›Full record

ArticleNature chemistry2025

Hydrophobic assembly of molecular catalysts at the gas-liquid-solid interface drives highly selective CO

Morgan McKee, Maximilian Kutter, Yue Wu, Hannah Williams, Marc-Antoine Vaudreuil, Mariolino Carta, Ashok Kumar Yadav, Harishchandra Singh, Jean-François Masson, Dieter Lentz and 2 more

Abstract read
PubMed Publisher
In one paragraph

Article in Nature chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. From COAngewandte Chemie (International ed. in English) · 2026
    Review
  6. Molecular Modification Strategies for Enhancing COMolecules (Basel, Switzerland) · 2025
    Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Morgan McKeeInstitute of Inorganic Chemistry, University of Bonn, Bonn, Germany.ORCID http://orcid.org/0000-0002-8636-5638
Maximilian KutterDepartment of Chemistry, Swansea University, Swansea, UK.ORCID http://orcid.org/0000-0002-5243-0817
Yue WuDepartment of Chemistry, Swansea University, Swansea, UK.
Hannah WilliamsDepartment of Chemistry, Université de Montréal, Montréal, Québec, Canada.
Marc-Antoine VaudreuilDepartment of Chemistry, Université de Montréal, Montréal, Québec, Canada.
Mariolino CartaDepartment of Chemistry, Swansea University, Swansea, UK.ORCID http://orcid.org/0000-0003-0718-6971
Ashok Kumar YadavSynchrotron SOLEIL, Beamline SIRIUS, Gif sur Yvette, France.ORCID http://orcid.org/0000-0003-2716-0971
Harishchandra SinghNano and Molecular Systems Research Unit, University of Oulu, Oulu, Finland.ORCID http://orcid.org/0000-0001-7754-5648
Jean-François MassonDepartment of Chemistry, Université de Montréal, Montréal, Québec, Canada.ORCID http://orcid.org/0000-0002-0101-0468
Dieter LentzFreie Universität Berlin, Institut für Chemie und Biochemie - Anorganische Chemie, Berlin, Germany.
Moritz F KühnelDepartment of Chemistry, Swansea University, Swansea, UK. moritz.kuehnel@uni-hohenheim.de.ORCID http://orcid.org/0000-0001-8678-3779
Nikolay KornienkoInstitute of Inorganic Chemistry, University of Bonn, Bonn, Germany. nikolay.kornienko@umontreal.ca.ORCID http://orcid.org/0000-0001-7193-2428

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Molecular catalysts offer tunable active and peripheral sites, rendering them ideal model systems to explore fundamental concepts in catalysis. However, hydrophobic designs are often regarded as detrimental for dissolution in aqueous electrolytes. Here we show that established cobalt terpyridine catalysts modified with hydrophobic perfluorinated alkyl side chains can assemble at the gas-liquid-solid interfaces on a gas diffusion electrode. We find that the self-assembly of these perfluorinated units on the electrode surface results in a catalytic system selective for electrochemical CO

Identifiers

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.